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Full Description
Updated reference on the field of organocatalysis explaining the many advances made in the past 10 years
Enantioselective Organocatalysis III presents easily accessible, summarized information on organocatalysis, from computational aspects to non-conventional strategies, with complete coverage of the main advances in the field in the past 10 years. The book is the continuation of Comprehensive Enantioselective Organocatalysis, retaining the main features of its predecessor but with a larger number of concise chapters. Experimental procedures are not presented in this edition as most of them are similar to those already discussed in the previous edition.
Edited by a highly qualified researcher and contributed to by experts in the field, Enantioselective Organocatalysis III includes information on:
Aminocatalysis-3 selected examples of aminocatalytic direct alpha-heteroatom functionalization and direct alpha-alkylation
Organocatalytic dynamic kinetic resolution and organocatalysis in carbohydrate synthesis and polymer science
Light-controlled organocatalysis by bifunctional single-catalyst systems and dual photo/organocatalytic strategies in asymmetric synthesis
Strategies towards asymmetric organocatalysis at parts-per-million loadings and emerging organocatalyst classes from renewable sources
Activation modes in asymmetric anion-binding catalysis and transformations with chiral phase-transfer catalysts
Appealing to a broad readership, Enantioselective Organocatalysis III is an essential reference for chemists and other researchers seeking to stay on top this rapidly developing field.
Contents
1. AMINOCATALYSIS
1.1 Explaining Anomalies in Enamine Catalysis: "Downstream Species" as a New Paradigm for Stereocontrol
1.2 Synergistic Strategies in Aminocatalysis
1.3 New trends in amino Acid-derived and Peptides Organocatalysts
1.4 Recent advances in amine catalyzed organocatalytic transformations
2. ENANTIOSELECTIVE CARBONYL CATALYSIS ENABLED BY CHIRAL ALDEHYDES
3. HYDROGEN-BOND DONOR CATALYSIS
3.1 Non-Classical C-H center dot center dot center dot X Hydrogen Bonding and Its Role in Asymmetric Organocatalysis
3.2 Chiral guanidines and thiourea derivatives in asymmetric synthesis
3.3 Squaramide-Catalyzed Asymmetric Reactions
3.4 Recent advances in asymmetric reactions catalyzed by chiral phosphoric acids
3.5 Dual Bronsted-acid Organocatalysis: Cooperative Asymmetric Catalysis with Combined Phosphoric and Carboxylic Acids
3.6 Brønsted acid catalysts and ?silylium? Lewis acid precatalysts Imidodiphosphorimidates (IDPis)
3.7 Stronger Bronsted Acids: Recent Progress (Akiyama, T and Mori, K)
4. PHOSPHINE ORGANOCATALYSIS
5. ION-PAIRING CATALYSIS
5.1 Activation Modes in Asymmetric Anion-Binding Catalysis
5.2 Asymmetric counteranion-directed catalysis (ACDC)
5.3 Phosphonium Salts in Asymmetric Catalysis: A Journey in a Decade's Extensive Research Work
5.4 Recent Progress in Asymmetric Ion-Pairing Catalysis with Ammonium Salts
6. PHASE-TRANSFER CATALYSTS
6.1 Design of high-performance chiral phase-transfer catalysts with privileged structures
6.2 Assisted by Hydrogen-Bond Donors: Cinchona Quaternary Salts as Privileged Chiral Catalysts for Phase-Transfer Reactions
6.3 Phase-Transfer and Ion-Pairing Catalysis of Pentanidiums and Bisguanidiniums
7. HALOGEN, CHALCOGEN
7.1 Halogen, Chalcogen, Anion-pi Bonding and sigma-Hole Interactions in Catalysis
7.2 Halogen Bonding in Organic Synthesis and Organocatalysis
7.3 Chalcogen Bonding: An Overview
8. SULFUR YLIDES
9. CHIRAL HYPERVALENT IODINES: ACTIVE PLAYERS IN ASYMMETRIC SYNTHESIS.
10. LEWIS BASE CATALYSIS PROMOTED NUCLEOPHILIC SUBSTITUTIONS -
RECENT ADVANCES AND FUTURE DIRECTIONS
11. ACTIVATING PRONUCLEOPHILES WITH HIGH PK(A) VALUES: CHIRAL ORGANO-SUPERBASES
12. RECENT ADVANCES IN THE CHEMISTRY AND APPLICATIONS OF N-HETEROCYCLIC CARBENES
13. ENANTIOSELECTIVE REDOX AND RADICAL REACTIONS IN THE DARK BY CHIRAL CATALYSTS
14. ORGANOCATALYSIS IN INERT C-H BOND FUNCTIONALIZATION
15. ENANTIOSELECTIVE DESYMMETRIZATION REACTIONS IN ASYMMETRIC CATALYSIS
16. TWO AND MORE CATALYSTS SYSTEMS
16.1 Two and Multi-organocatalyst Systems
16.2 Combined Power of Organo- and Transition Metal Catalysis in Organic Synthesis
16.3 Asymmetric Reactions Enabled by Cooperative Enantioselective Amino- and Lewis Acid Catalysis
16.4 Organocatalysis and Biocatalysis Hand in Hand: Combining Catalysts in One-Pot Procedures
17. RECENT PROGRESS IN ORGANOCATALYTIC ASYMMETRIC DOMINO TRANSFORMATIONS
18. MULTICOMPONENT AND MULTICATALYTIC REACTIONS -
A SYNTHETIC STRATEGY INSPIRED BY NATURE
19. STEREODIVERGENT ASYMMETRIC SYNTHESIS VIA ORGANOCATALYSIS
20. CATALYSTS RECOVERY STRATEGIES:
20.1 Fluorous organocatalysis
20.2 Covalently Supported Ionic Liquid Phases: An Advanced Class of Recyclable Catalytic Systems
20.3 Polymer Supported organocatalysts
21. SUPRAMOLECULAR CATALYSIS
21.1 Harnessing DNA as a Designable Scaffold for Asymmetric Catalysis: Recent Advances and Future Perspectives
21.2 Chitosan Based Catalyst and Their Mode of Action
21.3 Functionalized Macrocycles in Supramolecular Organocatalysis .
21.4 Nanopores of a Covalent Organic Framework: A Customizable Vessel for Organocatalysis
21.5 Asymmetric Catalysis Under 1D/2D Nanostructured Materials
21.6 Synthesis of Chiral Polymer Catalysts and Their Application to Asymmetric Reactions
21.7 Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts
21.7 Enabling protein-hosted organocatalytic transformations
22. SITE SELECTIVE AND REMOTE FUNCTIONALIZATION:
22.1 Recent advances in site-selective functionalization of carbohydrates mediated by organocatalysts
22.2 N-Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations
22.3 Advances in Organocatalytic 1,6-Addition Reactions: Enantioselective Construction of Remote Stereogenic Centers
22.4 Site-selective reactions mediated by molecular containers
23. NON-CONVENTIONAL ACTIVATION METHODS:
23.1 Mechanochemical Organocatalysis: Do High Enantioselectivities Contradict What We Might Expect?
23.2 Microwave-assisted Organo-catalyzed C-C and C-X (Heteroatom) Bond-forming Reactions
23.3 Modern Electrochemical Aspects for the Synthesis of Value-Added Organic Products
24. ORGANOCATALYSIS IN NON-CONVENTIONNAL MEDIAS
24.1 Organocatalysis in aqueous media
24.2 Chiral Ionic Liquids and Deep Eutectic Solvents in Asymmetric Synthesis
24.3 Application of Biobased Solvents in Asymmetric Catalysis (
25. LIGHT IN ORGANOCATALYSIS
25.1 Recent Trends in Photocatalytic Enantioselective Reactions
25.2 Organophotoredox catalysis : reactions and Structure-Property Relationships of catalysts
25.3 Photoredox Dual Catalysis
26. SWITCHABLE CATALYSTS : DYNAMIC RESPONSIVE SYSTEMS FOR CATALYTIC FUNCTION
27. EMERGING SYSTEMS:
27.1 Bio-Inspired Quinone Catalysis
27.2 Taurine: A Water Friendly Organocatalyst in Organic Reactions
27.3 Vitamin B1: A Versatile Organocatalyst for Organic Synthesis
27.4 Growing Impact of Carbohydrate-Based Organocatalysts
28. COMPUTATIONAL INSIGHTS
28.1 The Central Role of Nonbonding Interactions in Modern Covalent Organocatalysis
28.2 Transition State Models for Understanding the Origin of Chiral Induction in Asymmetric Catalysis
28.3 Catalyst Design Within Asymmetric Organocatalysis (
29. APPLIED ORGANOCATALYSIS:
29.1 Low-loading asymmetric organocatalysis
29.2 Asymmetric organocatalysis: an enabling technology for medicinal chemistry
29.3 New chemical processes to streamline carbohydrate synthesis
29.4 Organocatalytic Asymmetric Methodologies towards the Synthesis of Atropisomeric N-Heterocycles
29.5 Catalytic Enantioselective Construction of Spiro Quaternary Carbon Stereocenters
29.6 Organocatalyzed Asymmetric Synthesis of Axially, Planar, and Helical Chiral Compounds
29.7 Recent Advances in Organocatalytic Kinetic Resolution for the Synthesis of Functionalized Products
29.8 Recent applications of asymmetric organocatalytic annulation reactions in natural product synthesis
29.9 Green chemistry meets medicinal chemistry: a perspective on modern metal-free late-stage functionalization reactions
29.10 Synthesis of Cyclic Fragrances
29.11 Organocatalytic Atroposelective Synthesis of N-N Axially Chiral Indoles and Pyrroles by De Novo Ring Formation
29.12 Macromolecular architectures through organocatalysis
29.13 Flow Chemistry: Recent Developments in the Synthesis of Pharmaceutical Products
29.14 Asymmetric Organocatalytic Tandem/Domino Reactions to Access Bioactive Products
29.15 Synthesis of radio isotope labelled products with organocatalysis
30. VALORIZATION OF WASTE: SUSTAINABLE ORGANOCATALYSTS FROM RENEWABLE RESOURCES
31. HIGHLIGHTS OF THE RECENT PATENT LITERATURE: FOCUS ON ASYMMETRIC ORGANOCATALYSIS
