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Full Description
The discovery and evolution of organometallic cluster chemsitry is a major event in the development of inorganic chemistry. This volume focuses on the chemistry of the early transition elements in their lower and middle oxidation states: halide; sulfide; oxide; phosphate; alkoide; and related o-donor ligands. The key feature linking all these complexes in metal-metal bonding is the presence of pi-donor ligands. This book should be of interest to inorganic chemists and materials scientists.
Contents
Halide-supported octahedral clusters of zirconium - structural and bonding questions; cluster and metal-metal bonded chains in molybdenum oxide systems; chalcogenide cluster complexes of early transition metals; alkoxide clusters in molybdenum and vanadium phosphate solids; organophosphonate and organoarsonate complexes with the oxovanadium and oxomolybdenum. (Part contents).