Description
This book offers a comprehensive overview of recent theoretical studies on rhodium-catalyzed C-H functionalization, a topic that has attracted considerable attention over the years. It includes a brief experimental history, elementary reactions, and theoretical perspectives and describes in detail recent advanced computational studies on different types of Rh-catalyzed C-H functionalization, the underlying mechanisms, and the origin of regioselectivity in a series of such reactions. Providing examples shows readers how to use theoretical tools to solve problems related to mechanisms of organometallic reactions. As such, the book is an interesting and useful resource for a wide readership in various fields involving synthetic organic, organometallic, and catalysis reactions.
Table of Contents
Rh-catalyzed C-H functionalization.- Elementary reactions in Rh-catalyzed C-H functionalization.- Theoretical view of Rh-catalyzed C-C bond formation via C-H functionalization.- Theoretical view of Rh-catalyzed C-X bond formation via C-H functionalization.- Theoretical view of Rh-catalyzed hydrogenation via C-H functionalization.
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