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Description
Comprehensive presentation of upconversion luminescent materials, from fundamental theory to photovoltaic, photocatalytic, and biological applications
Photoenergy Conversion-Enhanced Perovskite Solar Cells is a thorough guide to the synthesis and properties of lanthanide-based and triplet-triplet annihilation-based upconversion nanomaterials. The book reviews their diverse applications in the fields of photovoltaics, luminescent solar concentrator, photodetectors, photocatalysis, lasing, light-emitting diodes, high-resolution bioimaging, photothermal therapy, photoelectrochemical biosensors, optical temperature sensing, ion detection, anti-counterfeiting, förster resonant energy transfer, volumetric full-color displays, photonic quantum logic gates, and other optical fields.
Photoenergy Conversion-Enhanced Perovskite Solar Cells explores sample topics including:
- Challenges in spectral response and photon management of perovskite photovoltaics (PVs)
- Down-conversion and down-shifting for high-energy uv utilization, with information on semiconductor oxides and carbon materials
- Surface plasmon resonance for light-harvesting, covering basic mechanisms as well as metal alloys and nanostructures
- Texturing for light-trapping, discussing electron transport layers with periodic nanostructures and texturing on glass or a transparent conductive oxide
- Luminescent solar concentrators for light concentration, reviewing both Pb-based and Pb-free nanocrystals
Photoenergy Conversion-Enhanced Perovskite Solar Cells is an essential reference for scientists, engineers, industrial experts, and advanced students to solve fundamental and applied problems of upconversion luminescent materials and think of new innovative ideas in the field of application of phosphor materials.
Table of Contents
Preface viii
1 Photon Energy Conversion Enhances Perovskite Photovoltaics 1
1.1 The Growing Global Energy Crisis and the Role of PVs 1
1.1.1 The Global Energy Crisis 1
1.1.2 The Role of PVs 1
1.1.3 Challenges and Future Outlook 3
1.2 Emergence of Perovskite Photovoltaics 3
1.2.1 Historical Development and Key Technological Milestones 3
1.2.2 Subsequent Years Witnessed a Series of Breakthroughs 4
1.2.3 Advantages of Perovskite Photovoltaics 5
1.2.4 Challenges and Future Prospects 7
1.3 Challenges in Spectral Response and Photon Management of Perovskite Photovoltaics 9
1.3.1 Limited Spectral Utilization 9
1.3.2 Photon Management Challenges 10
1.3.2.1 Surface Reflection and Light Scattering 10
1.3.2.2 Light Trapping and Optical Path Optimization 10
1.3.2.3 Parasitic Absorption and Losses in Non-active Layers 10
1.3.2.4 Emerging Solutions and Future Directions 10
1.4 Photon Management Strategies: Addressing Energy Losses in PSCs 11
1.4.1 UC and DC 11
1.4.2 Tandem and Graded Structures 11
1.4.3 Plasmonic Enhancements 12
1.4.4 Texturing and Light-Trapping Structures 12
1.4.5 Antireflective Coatings 12
1.4.6 Luminescent Solar Concentrators (LSCs) 12
1.5 The Scope of This Work 12
1.6 Structure of the Book 13
References 13
2 UC for Light Spectrum Expansion in Perovskite Photovoltaics 17
2.1 UC Integrated in Electron Transporting Layers 21
2.2 UC Integrated in Hole Transporting Layers 23
2.3 UC Integrated in Perovskite Photoactive Layer 24
2.4 UC Applied Outside Device Structure of PSCs 26
2.5 Chapter Summary 28
References 29
3 Down-Conversion/Downshifting for High-Energy UV Utilization in Perovskite Photovoltaics 37
3.1 Basic in Down-Conversion/Down-Shifting Improved Solar Cells 37
3.2 REs-Based DC Phosphors 41
3.3 Semiconductor Oxides 43
3.4 Organic Fluorescent Materials for DS in PSCs 44
3.5 Nanocrystals or Quantum Dots 47
3.6 Carbon Materials 48
3.7 Chapter Summary 49
References 50
4 Surface Plasmon Resonance for Light-Harvesting in Perovskite Photovoltaics 61
4.1 Basic Mechanisms in Surface Plasmon Resonance (SPR) 61
4.1.1 Far-Field Scattering Effect 63
4.1.2 Near-Field Enhancement 64
4.1.3 Plasmon Resonant Energy Transfer 65
4.2 Metals Nanostructures 66
4.2.1 Metal Nanoparticles 66
4.2.2 Metal Nanostructures with Varied Shapes 69
4.2.3 Novel Metal Plasmonic Nanostructures 70
4.3 Metal@Dielectric Composites 72
4.4 Metal Alloys 75
4.5 Other Nanostructures 76
4.6 Chapter Summary 78
References 79
5 Tandem Structure for Optical Complementarity in Perovskite Photovoltaics 89
5.1 Working Principle of Tandem Solar Cells 92
5.2 All-Perovskite Tandem Solar Cell 94
5.3 Perovskite/Organic Tandem Solar Cell 97
5.4 Perovskite/Quantum Dot or Perovskite/Dyes Tandem Solar Cell 99
5.5 All-Perovskite Triple-Junction Solar Cells 101
5.6 Perovskite/Perovskite/Perovskite Triple-Junction Solar Cell 104
5.7 Perovskite/Perovskite/Silicon Triple-Junction Solar Cell 110
5.8 Perovskite/Perovskite/Organic Configurations Triple-Junction Solar Cell 119
5.9 Chapter Summary 120
References 121
6 Texturing for Light-Trapping in Perovskite Photovoltaics 133
6.1 Texturing on Glass or Transparent Conductive Oxide 134
6.2 Electron Transport Layers with Periodic Nanostructures 137
6.3 Texturing of Perovskite Films 139
6.4 Interface Between the Hole Transport Layer and the Metal Back Electrodes 142
6.5 Chapter Summary 145
References 146
7 Antireflection for Photon Recycling Utilization in Perovskite Photovoltaics 155
7.1 Antireflection in Incident Side 156
7.2 Antireflection in Tandem Solar Cells 160
7.3 Antireflection for Colorful PSCs 162
7.4 Chapter Summary 163
References 165
8 Luminescent Solar Concentrators for Light Concentration 173
8.1 Introduction to Luminescent Solar Concentrators 173
8.2 Challenges and Innovations in LSC Efficiency 175
8.3 Pb-Based Perovskite Nanocrystals in LSCs 175
8.4 Pb Free-Perovskite Nanocrystals in LSCs 180
8.5 Chapter Summary 180
References 181
9 Conclusion and Perspectives for Photon Energy Conversion in Perovskite Photovoltaics 187
9.1 Perspectives 188
References 190
Index 195
