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Full Description
Now including Supplement 1, "Comprehensive Asymmetric Catalysis" critically reviews methods for the catalytic preparation of chiral organic compounds. This major reference set presents the state-of- the-art in this area. The internationally acclaimed editors and the contributors, who are recognized experts in the field, guarantee the authoritative and timely coverage. This set is not only the principal reference source for synthetic organic chemists, but also for all scientific researchers who require chiral compounds in their work (for example in biochemical investigations and molecular medicine) as well as for pharmaceutical chemists, agricultural chemists and other industrial researchers who prepare chiral compounds. The CD-ROM includes the full text search and a state-of-the-art graphic substructure search routine for compounds and reactions. Thus, enhancing the value of the book set. Since the publication of the 1st edition in 1999 research rapidly went on. These results are summarized in the first supplement which is now included.
Contents
Contents: 1 Introduction ,- 2 Historical Perspective ,- 3 Basic Principles of Asymmetric Synthesis ,- 4 General Aspects of Asymmetric Catalyis ,- 4.1 Non-Linear Effects and Autocatalysis ,- 5 Hydrogenation of Carbon-Carbon Double Bonds ,- 5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds ,- 5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds ,- 6 Reduction of Carbonyl and Imino Groups ,- 6.1 Hydrogenation of Carbonyl Groups ,- 6.2 Hydrogenation of Imino Groups ,- 6.3 Hydrosilylation of Carbonyl and Imino Groups ,- 6.4 Hydroboration of Carbonyl Groups ,- 7 Hydrosilylation of Carbon-Carbon Double Bonds ,- 8 Hydroalumination of Carbon-Carbon Double Bonds ,- 9 Hydroboration of Carbon-Carbon Double Bonds ,- 10 Hydrocyanation of Carbon-Carbon Double Bonds ,- 11 Hydrocarbonylation of Carbon-Carbon Double Bonds ,- 12 Hydrovinylation of Carbon-Carbon Double Bonds ,- 13 Carbometalation of Carbon-Carbon Double Bonds ,- 14 Heck Reaction ,- 15 Pauson-Khand Type Reactions ,- 16 Cyclopropanation and C-H Insertion Reactions ,- 16.1 Cyclopropanation and C-H Insertion with Cu ,- 16.2 Cyclopropanation and C-H Insertion with Rh ,- 16.3 Cyclopropanation and C-H Insertion with Metals Other Than Cu and Rh ,- 17 Aziridination ,- 18 Epoxidation ,- 18.1 Epoxidation of Allylic Alcohols ,- 18.2 Epoxidation of Alkenes Other Than Allylic Alcohols ,- 18.3 Epoxide Formation of Enones and Aldehydes ,- 19 Oxidation of Sulfides ,- 20 Dihydroxylation of Carbon-Carbon Double Bonds ,- 21 C-H Oxidation ,- 22 Bayer-Villiger Reaction ,- 23 Isomerization of Carbon-Carbon Double Bonds ,- 24 Allylic Substitution Reactions ,- 25 Cross Coupling Reactions ,- 26 Alkylation of Carbonyl and Imino Groups ,- 26.1 Alkylation of Carbonyl Groups ,- 26.2. Alkylation of Imino Groups ,- 27 Allylation of Carbonyl Groups ,- 28 Cyanation of Carbonyl and Imino Groups ,- 29 Aldol Reactions ,- 29.1 Mukaiyama Aldol Reaction ,- 29.2 Addition of Isocyanocarboxylates and Aldehydes ,- 29.3 Nitroaldol Reaction ,- 30 Addition of Acyl Carbanion Equivalents to the Carbonyl Groups and Enones ,- 31 Conjugate Addition Reactions ,- 31.1 Conjugate Addition of Organometallic Reagents ,- 31.2 Conjugate Addition of Stabilized Carbanions ,- 32 Ene-Type Reactions ,- 33 Cycloaddition Reactions ,- 33.1 Diels-Alder Reactions ,- 33.2 Hetero Diels-Alder and Related Reactions ,- 33.3 (2+2) Cycloaddition Reactions ,- 34 Additions to Enolates ,- 34.1 Alkylation of Enolates ,- 34.2 Protonation of Enolates ,- 35 Ring Opening of Epoxides and Related Reactions ,- 36 Polymerization Reactions ,- 37 Heterogeneous Catalysis ,- 38 Catalyst Immobilization ,- 38.1 Catalyst Immobilization: Solid Supports ,- 38.2 Catalyst Immobilization: Two-Phase Systems ,- 39 Combinatorial Approaches ,- 40 Catalytic Antibodies ,- 41 Industrial Applications ,- 41.1 The Chiral Switch of Metolachlor ,- 41.2 Process R&D of Pharmaceuticals, Vitamins and Fine Chemicals ,- 41.3 Cyclopropanation ,- 41.4 Asymmetric Isomerization of Olefi
