Gmelin: Handbook of Inorganic and Organometallic Chemistry （8TH）

Dahlenburg, Lutz/ Schumann, Hans/ Winter, Manfred

Springer-Verlag Berlin and Heidelberg GmbH & Co. K（1993/09発売）

• 製本 Hardcover:ハードカバー版／ページ数 332 p.
• 言語 ENG
• 商品コード 9783540936701
• DDC分類 546

Full Description

This volume completes the description of compounds with one 5LMo(CO)2 fragment (where L is a ligand bonded to molybdenom by five carbon atoms) and specifically deals with heteronuclear compounds containing one 5LMo(CO)2, fragment (5L being mostly C5H5) and one or more other transition metal fragment. These include many heterotrinuclear compounds with one MoM2 or MOMM' triangle capped by one CR or ERn group, thereby forming a tetrahedron. Many of the heteronuclear compounds were characterized by their molecular structure. The second part of the volume begins with a description of compounds containing one 5LMo(CO)3 fragment and is dominated by complexes containing the cyclopentadienyl ring or dienyl systems derived by substitution. The compounds described in this volume include the [C5H5Mo(CO)3]+ cation and its derivatives: its weakly solvated forms and C5H5Mo(CO)3X (X is a weakly co-ordinated anion); the radical C5H5Mo(CO)3; the anion [C5H5Mo(CO)3] with various counterions, and the hydride C5H5Mo(CO)3H.