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The volume describes the complexes of gallium with water, alcohols, aldehydes, ketones, quinones, ethers, O-heterocycles, carboxylic acids, ammine, amines, and N-heterocycles containing one nitrogen atom in the ring. Many of these complexes are of fundamental importance in the industrial and analytical chemistry of gallium. A large number of publications describe the separation and quantification of gallium in the form of co-ordination compounds. This often involves extended solvent extraction studies. The present volume offers a state-of-the-art description of the complexes formed in both analytical procedures and industrial processes and will help the reader understand the fundamental chemistry involved. Certain gallium complexes are used in pharmacology. Complexes with the radionucleide 67Ga were tested to diagnose to locate malignant tumours. A widely used complex is 67 gallium (III) citrate. This and other complexes described in this volume were also tested as anti-cancer chemotherapeutic agents.