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Full Description
This volume covers all of the chemical, physical and catalytic properties of over 1000 mononuclear unbridged di-and tri-substituted ferrocenes. Central chiral nomenclature is employed for optically active compounds. It describes di-and tri-substituted ferrocenes with P-containing substituents. Their importance is based on their ability to influence the course of synthetic reactions for organic compounds as ligands of transition metal complexes, particularly for Ni, Co, Rh and Pd complexes. The chiral ferrocenylphosphines are of special interest in that their optically active forms catalyze asymmetric syntheses in which compounds of high optical purity can be obtained (up to >90% ee).
