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Description
Aimed at graduate students and researchers, this unique text provides a reliable and practical guide to understanding and mastering complex synthesis pathways, explaining essential reaction principles and reagent classifications. 1. Introduction
PART 1. NUCLEOPHILIC REACTIONS
2. Reactions of alkylating compounds (A) with nucleophilic agents (1?5)
3. Reactions of electrophilic compounds containing a double bond between atoms of different electronegativity (B) with nucleophilic agents (1?5)
4. Reactions of electrophilic alkenes (C) with nucleophilic agents (1?5)
5. Reactions of aromatic compounds (D) with nucleophilic agents (1?5)
6. Reactions of compounds with an electrophilic center on a heteroatom (E) with nucleophilic agents (1?5)
PART 2. ELECTROPHILIC REACTIONS
7. Interactions of nucleophilic compounds (A?C) with inorganic cations (1)
8. Interactions of nucleophilic compounds (A?C) with uncharged electrophilic agents (2)
9. Reactions of nucleophilic compounds (A?C) with carbocations (3)
10. Reactions of aromatic compounds (D) with electrophilic agents (1?3)
11. Reactions of nucleophilic compounds (A?D) with organic cations carrying a charge on a heteroatom (4)
12. Reactions of nucleophilic compounds (A?D) with electrophilic carbenes (5)
13. Rearrangements of electron-deficient nitrogen compounds
PART 3. RADICAL REACTIONS
15. Methods of radical generation
16. Substitution reactions
17. Radical addition to unsaturated bonds
PART 4. PERICYCLIC REACTIONS
18. Diels?Alder reaction
19. 1,3-Dipolar cycloaddition reactions
20. [2+2] Cycloaddition reactions
21. Ene reactions
22. Sigmatropic rearrangements
Mieczyslaw Makosza was the Director of the Institute of Organic Chemistry at the Polish Academy of Sciences in Warsaw (Poland) from 1979 until his retirement in 2004. He earned his M.Sc. from the University of St. Petersburg (Russia) in 1956, a Ph.D. from the Warsaw Technical University in 1963, and his habilitation in 1967. He is a renowned organic synthesis expert. He was one of the pioneers of phase-transfer catalysis methodology, which has found widespread application in research laboratories and industry. He also developed a general concept for nucleophile reactions with electron-deficient arenes. Professor Makosza has received numerous awards, including the Alexander von Humboldt Research Award, and earned honorary doctorates from universities in the United States, France, Russia, and Poland.
Michal Fedorynski was a professor of organic chemistry at Warsaw Technical University (Poland) until his retirement in 2016. He earned his M.Sc. (1969) and Ph.D. (1974) from Warsaw University of Technology, working with Professor Mieczyslaw Makosza. In 1979, he spent 15 months as a postdoc with Professor Robert A. Moss at Rutgers University, USA. His research interests include phase-transfer catalysis and the chemistry of carbanions and dihalocarbenes, significantly advancing the field of organic synthesis.
