- ホーム
- > 洋書
- > ドイツ書
- > Mathematics, Sciences & Technology
- > Chemistry
- > miscellaneous
Full Description
Guide to the design, synthesis, and applications of core-shell nanoparticles
Core-Shell Nanomaterials provides a thorough exploration of core-shell nanomaterials, detailing their fundamental architectures and synthesis methods (e.g., sol-gel, hydrothermal), advanced characterization techniques (TEM, XRD), and applications in energy (batteries, solar cells), environment (water purification, carbon capture), and biomedicine (drug delivery, theranostics). Emerging trends like smart coatings and additive manufacturing are highlighted, alongside challenges such as toxicity, cost, and regulatory hurdles.
Written by a team of highly qualified authors, Core-Shell Nanomaterials includes information on:
Unique properties of core-shell structures, including structural and morphological characteristics, enhanced stability and core protection, and tunable optical and electronic properties
Physical methods for core-shell synthesis including sputtering and pulsed laser deposition, mechanical milling and ball milling, and electrospinning and physical encapsulation
Scalability and cost-effective manufacturing, covering batch versus continuous production, challenges in quality control, and automated and AI-driven synthesis methods
Microscopy characterization techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and forced ion beam (FIB) and 3D imaging techniques
Thermal and mechanical analysis through thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), nanoindentation, and dynamic mechanical analysis (DMA)
By drawing from both academic research and emerging industrial trends, Core-Shell Nanomaterials serves as a valuable reference for graduate students, researchers, and professionals in materials science, nanotechnology, chemistry, and engineering seeking a multidimensional perspective on the future trajectory of these exciting nanomaterials.
Contents
About the Authors xiii
Preface xv
Acknowledgements xvii
Disclosure of AI Use xix
1 Introduction to Core-shell Nanomaterials 1
1.1 Basic Concept of Core-shell Structures 2
1.2 Historical Development of Core-shell Materials 3
1.3 Unique Properties of Core-shell Structures 6
1.3.1 Structural and Morphological Characteristics 7
1.3.2 Enhanced Stability and Core Protection 8
1.3.3 Controlled Surface Chemistry and Functionalization 9
1.3.4 Tunable Optical and Electronic Properties 11
1.3.5 Magnetic and Catalytic Synergies 12
1.3.6 Mechanical Strength and Durability Enhancements 14
1.4 Role in Advancing Nanotechnology 15
1.4.1 Energy Storage and Conversion 16
1.4.2 Environmental Applications and Sustainability 18
1.4.3 Biomedical Innovations and Drug Delivery 19
1.4.4 Electronics, Photonics, and Wearable Technologies 21
1.4.5 Emerging Fields and Future Prospects 23
1.5 Conclusion 24
2 Fundamentals of Core-shell Nanomaterials 33
2.1 Core-shell Configurations and Types 34
2.1.1 Solid Core-shell Structures 35
2.1.2 Hollow Core-shell Structures 37
2.1.3 Multi-shell (Layered) Architectures 38
2.1.4 Janus and Asymmetric Core-shell Systems 39
2.1.5 Core-shell Hybrid and Composite Nanostructures 41
2.2 Theoretical Basis of Core-shell Interactions 42
2.2.1 Interfacial Phenomena in Core-shell Materials 43
2.2.2 Electronic and Optical Coupling Between Core and Shell 44
2.2.3 Mechanical and Thermal Stability Considerations 46
2.2.4 Core-shell Effects on Catalysis and Reactivity 48
2.2.5 Computational and Modeling Approaches in Core-shell Systems 49
2.3 Core-shell Material Compositions 52
2.3.1 Metallic Core-shell Nanostructures 52
2.3.2 Polymeric Core-shell Systems 53
2.3.3 Metal Oxide-based Core-shell Nanostructures 53
2.3.4 Hybrid and Composite Core-shell Materials 54
2.4 Structure-Property Relationships in Core-shell Materials 55
2.4.1 Influence of Core and Shell Thickness on Properties 55
2.4.2 Effect of Core-shell Interfaces on Mechanical and Thermal Stability 57
2.4.3 Optical and Electronic Properties of Core-shell Architectures 59
2.4.4 Magnetic and Catalytic Performance Optimization 60
2.4.5 Tunability of Properties Through Shell Modification 62
2.5 Conclusion 64
3 Synthesis of Core-shell Nanomaterials 73
3.1 Physical Methods for Core-shell Synthesis 74
3.1.1 PVD and Thermal Evaporation 74
3.1.2 Sputtering and PLD 76
3.1.3 Mechanical Milling and Ball Milling Approaches 77
3.1.4 Electrospinning and Physical Encapsulation Techniques 79
3.1.5 Template-assisted Physical Synthesis 80
3.2 Chemical Methods for Core-shell Synthesis 81
3.2.1 Sol-Gel Method and Controlled Precipitation 82
3.2.2 Hydrothermal and Solvothermal Approaches 84
3.2.3 Coprecipitation and Layer-by-layer Assembly 84
3.2.4 Chemical Vapor Deposition 86
3.2.5 Colloidal Synthesis and Wet-chemical Techniques 87
3.3 Green and Sustainable Synthesis Approaches 88
3.3.1 Biogenic and Plant-based Synthesis of Core-shell Nanomaterials 89
3.3.2 Use of Non-toxic and Eco-friendly Precursors 91
3.3.3 Energy-efficient and Low-temperature Processing 92
3.3.4 Waste Utilization and Recycling in Core-shell Synthesis 93
3.3.5 Water-based and Solvent-free Synthesis Strategies 94
3.4 Scalability and Cost-efficient Manufacturing 95
3.4.1 Batch vs. Continuous Production Techniques 96
3.4.2 Large-scale Industrial Synthesis of Core-shell Nanomaterials 97
3.4.3 Cost and Energy Considerations in Scale-up 99
3.4.4 Challenges in Mass Production and Quality Control 100
3.4.5 Automated and AI-driven Synthesis Methods 102
3.5 Emerging Trends in Synthesis Strategies 103
3.6 Conclusion 104
4 Characterization Techniques for Core-shell Nanomaterials 113
4.1 Microscopy Techniques 114
4.1.1 SEM for Morphology Analysis 114
4.1.2 TEM and High-resolution TEM 116
4.1.3 AFM for Surface Analysis 117
4.1.4 FIB and 3D Imaging Techniques 118
4.2 Spectroscopy Techniques 120
4.2.1 UV-Vis and PL Spectroscopy 121
4.2.2 Raman Spectroscopy and Surface-enhanced Raman Spectroscopy 122
4.2.3 Fourier Transform Infrared Spectroscopy 124
4.2.4 XPS for Surface Composition Analysis 126
4.2.5 EDS for Elemental Mapping 127
4.3 Thermal and Mechanical Analysis 128
4.3.1 Thermogravimetric Analysis (TGA) for Stability Testing 129
4.3.2 DSC for Phase Transition Studies 129
4.3.3 Nanoindentation for Mechanical Property Evaluation 131
4.3.4 Dynamic Mechanical Analysis and Stress-Strain Behavior 131
4.4 Real-time Monitoring and In Situ Characterization 132
4.4.1 In Situ TEM and Operando Microscopy for Dynamic Analysis 133
4.4.2 In Situ Spectroscopy for Reaction Mechanism Studies 134
4.4.3 Real-time Surface and Interface Monitoring Techniques 134
4.4.4 Environmental and Live-cell Imaging for Bioapplications 135
4.5 Advanced Characterization Techniques 136
4.5.1 Synchrotron-based X-ray Techniques for Nanoscale Analysis 137
4.5.2 Neutron Scattering and Magnetic Property Investigations 138
4.5.3 Cryo-EM and Super-resolution Imaging in Core-shell Studies 139
4.5.4 AI-driven and Machine Learning Approaches in Material Characterization 139
4.6 Conclusion 140
5 Core-shell Nanomaterials for Energy Applications 147
5.1 Introduction 147
5.2 Photovoltaics: Enhancing Solar Cell Efficiency 149
5.3 Energy Storage: Batteries, Supercapacitors, and Fuel Cells 152
5.4 Hydrogen Generation and Storage Systems 155
5.5 Electrocatalysis and Photocatalysis 158
5.6 Conclusion 162
6 Core-shell Nanomaterials in Environmental Applications 169
6.1 Introduction 169
6.2 Core-shell Nanomaterials for Water Purification 172
6.2.1 Adsorption Techniques 172
6.2.2 Filtration Applications 175
6.2.3 Photocatalysis for Water Treatment 177
6.3 Core-shell Nanomaterials for Air Quality Improvement 181
6.3.1 Pollutant Removal 181
6.3.2 Gas Sensors 182
6.4 Core-shell Nanomaterials for CCS 183
6.5 Core-shell Nanomaterials in Waste Management and Recycling 185
6.5.1 Waste Treatment and Resource Recovery 185
6.5.2 Biodegradable and Sustainable Core-shell Materials 187
6.6 Challenges and Future Perspectives 188
6.6.1 Scalability and Economic Considerations 188
6.6.2 Environmental Impact and Toxicity Concerns 188
6.6.3 Future Trends in Core-shell Environmental Nanotechnology 189
6.7 Conclusion 189
7 Biomedical Applications of Core-shell Nanostructures 195
7.1 Introduction to Biomedical Applications 195
7.2 Targeted Drug Delivery Systems 198
7.2.1 Mechanism of Targeted Drug Delivery 198
7.2.2 Types of Core-shell Nanostructures for Drug Delivery 200
7.2.3 Examples of Effective Core-shell Systems 201
7.3 Bioimaging and Diagnostics 203
7.3.1 Role of Core-shell Materials in Bioimaging 203
7.3.2 Core-shell Materials in Diagnostics 205
7.3.3 Applications in Early-stage Disease Detection 206
7.3.4 Examples of Core-shell Materials in Bioimaging and Diagnostics 208
7.4 Theranostics: Combining Therapy and Diagnostics 209
7.4.1 Concept of Theranostics 209
7.4.2 Mechanisms in Theranostics 210
7.4.3 Examples of Nanomaterials Used and Applications in Cancer Theranostics 212
7.5 Biocompatibility and Safety Assessment 213
7.6 Conclusion 216
8 Emerging Applications of Core-shell Nanomaterials 223
8.1 Introduction 223
8.2 Smart Coatings and Functional Textiles 226
8.2.1 Mechanism and Functionality 226
8.2.2 Applications in Protective and Smart Surfaces 227
8.3 Sensors and Actuators 229
8.3.1 Core-shell Nanomaterials in Sensors 229
8.3.1.1 Mechanism of Signal Enhancement Using Core-shell Systems 230
8.3.1.2 Detection of Environmental Pollutants, Gases, and Biomolecules 230
8.3.1.3 Advantages of Core-shell Nanomaterials in Sensors 231
8.3.2 Actuator Applications 231
8.3.2.1 High-performance Actuators in Robotics and Adaptive Systems 231
8.3.2.2 Role in Precision Movements and Responsiveness 232
8.3.2.3 Applications in High-performance Actuators 233
8.4 Optoelectronics and QDs 234
8.4.1 Role of Core-shell Nanomaterials 234
8.4.2 QDs-based Core-shell Systems 235
8.5 3D Printing and Additive Manufacturing 237
8.5.1 Role of Core-shell Nanomaterials in 3D Printing 237
8.5.2 Applications in Customized Devices and Prototypes 239
8.6 Conclusion 241
9 Challenges and Opportunities in Core-shell Nanotechnology 247
9.1 Introduction 247
9.2 Synthesis Complexity and Control Issues 249
9.3 Scalability and Industrialization Challenges 250
9.4 Environmental and Toxicological Concerns 253
9.5 Economic and Regulatory Barriers 255
9.5.1 Cost-related Challenges in the Commercialization of Core-shell Nanomaterials 255
9.5.2 Economic Feasibility in Manufacturing and Integrating These Materials into Existing Products 255
9.5.3 Regulatory Hurdles and Approval Processes for Nanomaterial-based Products 255
9.6 Emerging Trends in Core-shell Research 257
9.7 Integration with AI and ml 258
9.8 Interdisciplinary Approaches for Advanced Applications 260
9.9 Potential Breakthroughs in Energy, Environment, and Medicine 261
9.9.1 Energy Applications: Next-generation Energy Storage, Conversion, and Harvesting 262
9.9.2 Environmental Applications: Waste Treatment, Water Purification, and Pollution Control 262
9.9.3 Medical Applications: Targeted Drug Delivery, Theranostics, and Tissue Engineering 263
9.9.4 Future Opportunities for Core-shell Nanomaterials 263
9.10 Conclusion 264
Index 271
