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Guide to the design, synthesis, and applications of core-shell nanoparticles
Core-Shell Nanomaterials provides a thorough exploration of core-shell nanomaterials, detailing their fundamental architectures and synthesis methods (e.g., sol-gel, hydrothermal), advanced characterization techniques (TEM, XRD), and applications in energy (batteries, solar cells), environment (water purification, carbon capture), and biomedicine (drug delivery, theranostics). Emerging trends like smart coatings and additive manufacturing are highlighted, alongside challenges such as toxicity, cost, and regulatory hurdles.
Written by a team of highly qualified authors, Core-Shell Nanomaterials includes information on:
Unique properties of core-shell structures, including structural and morphological characteristics, enhanced stability and core protection, and tunable optical and electronic properties
Physical methods for core-shell synthesis including sputtering and pulsed laser deposition, mechanical milling and ball milling, and electrospinning and physical encapsulation
Scalability and cost-effective manufacturing, covering batch versus continuous production, challenges in quality control, and automated and AI-driven synthesis methods
Microscopy characterization techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and forced ion beam (FIB) and 3D imaging techniques
Thermal and mechanical analysis through thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), nanoindentation, and dynamic mechanical analysis (DMA)
By drawing from both academic research and emerging industrial trends, Core-Shell Nanomaterials serves as a valuable reference for graduate students, researchers, and professionals in materials science, nanotechnology, chemistry, and engineering seeking a multidimensional perspective on the future trajectory of these exciting nanomaterials.
Contents
About the Authors xiii
Preface xv
Acknowledgements xvii
Disclosure of AI Use xix
1 Introduction to Core-shell Nanomaterials 1
1.1 Basic Concept of Core-shell Structures 2
1.2 Historical Development of Core-shell Materials 3
1.3 Unique Properties of Core-shell Structures 6
1.4 Role in Advancing Nanotechnology 15
1.5 Conclusion 24
2 Fundamentals of Core-shell Nanomaterials 33
2.1 Core-shell Configurations and Types 34
2.2 Theoretical Basis of Core-shell Interactions 42
2.3 Core-shell Material Compositions 52
2.4 Structure-Property Relationships in Core-shell Materials 55
2.5 Conclusion 64
3 Synthesis of Core-shell Nanomaterials 73
3.1 Physical Methods for Core-shell Synthesis 74
3.2 Chemical Methods for Core-shell Synthesis 81
3.3 Green and Sustainable Synthesis Approaches 88
3.4 Scalability and Cost-efficient Manufacturing 95
3.5 Emerging Trends in Synthesis Strategies 103
3.6 Conclusion 104
4 Characterization Techniques for Core-shell Nanomaterials 113
4.1 Microscopy Techniques 114
4.2 Spectroscopy Techniques 120
4.3 Thermal and Mechanical Analysis 128
4.4 Real-time Monitoring and In Situ Characterization 132
4.5 Advanced Characterization Techniques 136
4.6 Conclusion 140
5 Core-shell Nanomaterials for Energy Applications 147
5.1 Introduction 147
5.2 Photovoltaics: Enhancing Solar Cell Efficiency 149
5.3 Energy Storage: Batteries, Supercapacitors, and Fuel Cells 152
5.4 Hydrogen Generation and Storage Systems 155
5.5 Electrocatalysis and Photocatalysis 158
5.6 Conclusion 162
6 Core-shell Nanomaterials in Environmental Applications 169
6.1 Introduction 169
6.2 Core-shell Nanomaterials for Water Purification 172
6.3 Core-shell Nanomaterials for Air Quality Improvement 181
6.4 Core-shell Nanomaterials for CCS 183
6.5 Core-shell Nanomaterials in Waste Management and Recycling 185
6.6 Challenges and Future Perspectives 188
6.7 Conclusion 189
7 Biomedical Applications of Core-shell Nanostructures 195
7.1 Introduction to Biomedical Applications 195
7.2 Targeted Drug Delivery Systems 198
7.3 Bioimaging and Diagnostics 203
7.4 Theranostics: Combining Therapy and Diagnostics 209
7.5 Biocompatibility and Safety Assessment 213
7.6 Conclusion 216
8 Emerging Applications of Core-shell Nanomaterials 223
8.1 Introduction 223
8.2 Smart Coatings and Functional Textiles 226
8.3 Sensors and Actuators 229
8.4 Optoelectronics and QDs 234
8.5 3D Printing and Additive Manufacturing 237
8.6 Conclusion 241
9 Challenges and Opportunities in Core-shell Nanotechnology 247
9.1 Introduction 247
9.2 Synthesis Complexity and Control Issues 249
9.3 Scalability and Industrialization Challenges 250
9.4 Environmental and Toxicological Concerns 253
9.5 Economic and Regulatory Barriers 255
9.6 Emerging Trends in Core-shell Research 257
9.7 Integration with AI and ML 258
9.8 Interdisciplinary Approaches for Advanced Applications 260
9.9 Potential Breakthroughs in Energy, Environment, and Medicine 261
9.10 Conclusion 264
Index 271
