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Full Description
Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.
Contents
Introduction: Preparation, Covalent Chemistry, Applications Receptors for Pristine Fullerenes: Cyclodextrines, Cycloveratrilenes, Calixarenes; Nanorings; Concave-Convex Interactions Supramolecular Chemistry of Porphyrins and C60 Supramolecular Chemistry of Crown Ethers and C60 H-Bonding Involving Fullerenes Fullerene-Containing Catenanes and Rotaxanes: Molecular Motors and Machinery Photophysics of Supramolecular Systems Involving Fullerenes and Carbon Nanotubes: Energy versus Electron Transfer Liquid Crystals, Micelles and Gels Self-Assembly on Surfaces: Self-Assembled Monolayers, Nanoparticles Organizing Fullerenes on Solid Surfaces with STM Ionic Motifs Applications of Supramolecular Ensembles with Fullerenes and CNTs: Solar Cells, Transistors Supramolecular Chemistry of CNTs and other Carbon Nanostructures Supramolecular Fullerene Polymers and Dendrimers Practical Aspects: Methods, Techniques, Practical Examples, Experimental Procedures
