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Full Description
This comprehensive review of cinchona-based chiralilty inducers and their applications covers every topic, including ligands, immobilization and organocatalysis. Each chapter summarizes the scope and limitations of the new methods and technologies, while the final chapter contains carefully selected working procedures of cinchona alkaloid-promoted reactions organized according to reaction type. Invaluable reading for anyone wanting to learn about the current state of this hot topic.
Contents
Preface. Biography. List of Contributors. 1 An Overview of Cinchona Alkaloids in Chemistry (Choong Eui Song). Part One: Cinchona Alkaloid Derivatives as Chirality Inducers in Metal-Catalyzed Reactions. 2 Cinchona Alkaloids as Chirality Transmitters in Metal-Catalyzed Asymmetric Reductions (Hans-Ulrich Blaser). 3 Cinchona Alkaloids as Chiral Ligands in Asymmetric Oxidations (David J. Ager). 4 Cinchona Alkaloids and their Derivatives as Chirality Inducers in Metal-Promoted Enantioselective Carbon-Carbon and Carbon-Heteroatom Bond Forming Reactions (Ravindra R. Deshmukh, Do Hyun Ryu, and Choong Eui Song). Part Two: Cinchona Alkaloid Derivatives as Chiral Organocatalysts. 5 Cinchona-Based Organocaalysts for Asymmetric Oxidations and Reductions (Ueon Sang Shin, Je Eun Lee, Jung Woon Yang, and Choong Eui Song). 6 Cinchona-Catalyzed Nucleophilic alpha-Substitution of Carbonyl Derivatives (Hyeung-geun Park and Byeong-Seon Jeong). 7Cinchona-Mediated Enantioselective Protonations (Jacques Rouden). 8 Cinchona-Catalyzed Nucleophilic 1,2-Addition to C=O and C=N Bonds (Hyeong Bin Jang, Ji Woong Lee, and Choong Eui Song). 9 Cinchona-Catalyzed Nucleophilic Conjugate Addition to Electron-Deficient C=C Double Bonds (Ji Woong Lee, Hyeong Bin Jang, and Choong Eui Song). 10 Cinchona-Catalyzed Cycloaddition Reactions (Yan-Kai Liu and Ying-Chun Chen). 11 Cinchona-Based Organocatalysts for Desymmetrization of meso-Compounds and (Dynamic) Kinetic Resolution of Racemic Compounds (Ji Woong Lee, Hyeong Bin Jang, Je Eun Lee, and Choong Eui Song). Part Three: Organic Chemistry of Cinchona Alkaloids. 12 Organic Chemistry of Cinchona Alkaloids (Hans Martin Rudolf Hoffmann and Jens Frackenpohl). Part Four: Cinchona Alkaloid and Their Derivatives in Analytics. 13 Resolution of Racemates and Enantioselective Analytics by Cinchona Alkaloids and Their Derivatives (Karol Kacprzak and Jacek Gawronski). Appendix: Tabular Survey of Selected Cinchona-Promoted Asymmetric Reactions(Ji Woong Lee and Choong Eui Song). Index.
