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基本説明
All chapters are revised and updated including new contents on green aspects e.g. green solvents and latest developments in techniques.
Full Description
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Contents
Preface PART IProperties of Solvents Classifications of Solvents Effects of Solvent Dissolution Some Fundamental Aspects of Ion-Solvation Comparison of Ionic Solvation Energies in Different Solvents and Solvent Effects on Ionic Reactions and Equilibria Solvent Effects on the Complexation of Metal Ions Selective Solvation of Ions in Mixed Solvents Ion Association and Solvent Acid-Base Reactions pH-Scales in Non-Aqueous Solutions REDOX REACTIONS IN NON-AQUEOUS SOLVENTS Solvent Effects on Various Types of Redox Reactions Redox Properties of Solvents and Potential Windows Redox Titrations in Non-Aqueous Solutions PART II: Electrochemical Techniques and Their TECHNIQUES Classification of Electrochemical Techniques Fundamentals of Electrode Reactions and Current-Potential Relations DC Polarography - Methods that Electrolyze Electroactive Species Only Partially New Types of Polarography - Methods that Electrolyze Electroactive Species Only Partially Voltammetry and Related New Techniques - Methods that Electrolyze Electroactive Species Only Partially Electrogravimetry and Coulometry - Methods that Completely Electrolyze Electroactive Species Potentiometry - A Method that Does Not Electrolyze Electroactive Species Conductimetry - A Method that is Not Based on Electrode Reactions Electrochemical Instrumentation - Roles of Operational Amplifiers and Microcomputers Non-Aqueous Solutions pH Measurements in Non-Aqueous Solutions Applications of Potentiometry in Non-Aqueous Solutions Liquid Junction Potentials between Electrolytes and Electrolytic Conductivity Ionic Conductivities and Solvents Applications of Conductimetry in Non-Aqueous Solutions POLAROGRAPHY AND Non-Aqueous Solutions Polarography and Voltammetry of Inorganic Species Polarography and Voltammetry of Organic Compounds Cyclic Voltammetry for Electrochemical Studies in Non-Aqueous Solutions Voltammetry of Isolated Nanoparticle Solutions (Nanoelectrochemistry) OTHER ELECTROCHEMICAL Techniques in Non-Aqueous Solutions Combinations of Electrochemical and IMPURITIES Influences of Solvent Impurities on Electrochemical Measurements Procedures for the Purification of Solvents Tests for Purity of Solvents Purification Methods for Solvents of Common Use SELECTION AND PREPARATION OF SUPPORTING ELECTROLYTES Selection of Supporting Electrolytes for Electrochemical Measurements Methods for Preparing and Purifying Supporting TECHNOLOGIES New Batteries Using Non-Aqueous Solutions (Lithium Batteries) New Capacitors Using Non-Aqueous Solutions Conducting Polymers and Electrochemistry in Non-Aqueous Solutions Electrochemiluminescence (ECL) Electrochemical Reduction of CO2 in Non-Aqueous Solvents Use of Acetonitrile in Electrowinning and Electrorefining of Copper Electrodeposition of Metals and Semiconductors from Non-Aqueous Solutions PART III: Electrochemistry in INTERFACES Interfaces between Two Immiscible Electrolyte Solutions Interfaces between Ionic-Liquids and Water
