Ｃ－Ｈ結合変換ハンドブック（全２巻） Handbook of C-H Transformations : Applications in Organic Synthesis, 2 volumes

Ｃ－Ｈ結合変換ハンドブック（全２巻）<br>Handbook of C-H Transformations : Applications in Organic Synthesis, 2 volumes

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Ｃ－Ｈ結合変換ハンドブック（全２巻）
Handbook of C-H Transformations : Applications in Organic Synthesis, 2 volumes

Dyker, Gerald(ed.)

ウェブストア価格 ¥106,125（本体¥96,478）
Wiley-VCH（2005/11発売）
外貨定価 EUR 399.00
ポイント 964pt

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製本 Hardcover:ハードカバー版／ページ数 650 p.
言語 ENG
商品コード 9783527310746

基本説明

The whole range of the functionalization of C-H-bonds is presented. Volume 1. I. General.- 1. What is C-H Bond Activation?- 2. C-H Transformation in Industrial Processes.- II. C-H Transformation at sp-Hybridized Carbon Atoms.- 1. C-H Transformation at Terminal Alkynes. - 2. Asymmetric Hydrocyanation of Alkenes.- III. C-H Transformation at sp2-hybridized Carbon Atoms.- 1. C-H Transformations at Arenes.- 2. C-H Transformation at Alkenes.- 3. C-H Transformation at Aldehydes and Imines. Volume 2.- IV. C-H Transformation at sp³-hybridized Carbon Atoms.- 1. C-H Transformation at Functionalized Alkanes.- 2. C-H Transformation at Unfunctionalized Alkanes.

Full Description

Here, the whole range of the functionalization of CH-bonds is presented for the first time in one handbook, with the focus throughout on topicality and practicability. Topics span modern catalysts for Friedel-Crafts type reactions to transition metal catalysts for the oxofunctionalization, via new methods for radicalic halogenation to domino processes by catalytic ortho metalation.
Renowned for his research as well as for his excellent articles and reviews, Gerald Dyker provides in these two volumes reliable and typical experimental procedures, thus lending the book great practical value.

INTRODUCTION AND BACKGROUND
CH ACTIVATION AT SP-HYBRIDIZED CARBON ATOMS
At terminal alkynes
- base-induced or catalyzed addition of terminal alkynes to elektrophiles
- Sonogashira coupling reaction
- Glaser coupling reaction
At HCN
- hydrocyanation of alkenes and alkynes
- enantioselective addition of HCN to carbonyl compounds
CH ACTIVATION AT SP2-HYBRIDIZED CARBON ATOMS
At arenes
- CO-bond formation by oxidation
- by stoichiometric oxidants
- by enzymes
- supported by artificial transition metal catalysts
- towards industrial application: addition to unfunctionalized olefines
- Rh-catalyzed carbonylation
- Rh-catalyzed and Pt-catalyzed silylation
- ortho-selective alkylation of arenes
- DOM reaction
- intermolecular Pd-catalyzed arylations
- Pd-catalyzed arylations via palladacycles
- oxidative vinylation: Pd-catalyzed in comparison to Rh-catalyzed processes
At alkenes
- via cyclometallated Ru-complexes (or: Ru-catalyzed activation of alkenyl esters)
- via cyclometallated Rh-complexes
- Heck reaction
- via cyclopalladation
- Wacker oxidation
At aldehydes
- via cyclopalladation
- via cyclometallation with rhodium catalysts
- inter- and intramolecular (enantioselective) hydroacylation
CH ACTIVATION AT SP3-HYBRIDIZED CARBON ATOMS
At functionalized alkanes
- in allylic and benzylic position
- via palladacycles
- via cyclometallated complexes
- in a-position of nitriles
- asymmetric aldol reactions and related reactions
- oxidative free-radical Cyclizations with b-dicarbonyl compounds
- aerobic oxidation of alcohols
At unfunctionalized alkanes
- CO-bond formation by oxidation
- radicalic halogenation
- photochemical processes
- heterogenic catalysis by silica supported hydrido tantalum
- Pd-catalyzed carboxylation
- olefines by transition metal catalyzed dehydrogenation