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Full Description
EUPOC 2003, European Polymer Conference on "Stereo specific Polymerization and Stereoregular Polymers" was held on June 8-12, 2003 in Milan, Italy. The symposium was organized to celebrate the centenary of the birth of Giulio Natta, who shared the 1963 Nobel Prize in Chemistry with Karl Ziegler. The symposium provided a forum to discuss: new results and perspectives on novel catalysts; and synthesis, structure, characterization, and applications of polyolefins. The symposium covered the following topics: traditional catalysts; metallocene catalysts; more recent catalysts; molecular modeling; polymerization mechanisms; structural aspects and properties of stereoregular polymers; and, new products and processes. This volume of Macromolecular Symposia is a collection of some of the lectures presented at the symposium and the opening lecture profiling Giulio Natta as a scientist and as a man.
Contents
Preface (A. Giarrusso, G. Ricci, I Tritto).1. Giulio Natta - His Life and Scientific Achievements (L. Porri).2. Precise Arguments on the Distribution of Stereospecific Active Sites on MgC12-Supported Ziegler-Natta Catalysts (B. Liu, et al.).3. Recent Data on the Number of Active Centers and Propagation Rate Constants in Olefin Polymerization with Supported ZN Catalysts (V. Zakharov, et al.).4. Comparison of Silyl Chromate and Chromium Oxide Based Olefin Polymerization Catalysts (K. Cann, et al.).5. Surface Physico-Chemical State of CO-Prereduced Phillips CrOx/SiO2 Catalyst and Unique Polymerization Behavior in the Presence of Al-Alkyl Cocatalyst (B. Liu, et al.).6. D/A-Metallocenes: The New Dimension in Catalyst Design (A. Starzewski).7. Microstructural Characteristics and Thermal Properties of ansa-Zirconcene Catalyzed Copolymers of Propene with Higher a-Olefins (M. Sacchi, et al.).8. Relative Reactivity Enhancement of (ME5Cp)2Zrc12 in Mixture with (1,2,4-Me3Cp)2ZrC1
