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Full Description
On-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry.
In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials.
Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices.
Chapters "Mechanistic insights into surface-supported chemical reactions", "Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels" and "Bottom-up fabrication of atomically precise graphene nanoribbons" of this book are available open access under a CC BY 4.0 license at link.springer.com
Contents
Preface.- Mechanistic insights into surface-supported chemical reactions.- Kinetic and thermodynamic considerations in on-surface synthesis.- Heat or light? Tools of choice for on-surface synthesis.- Reactivity on and of graphitic substrates at the liquid-solid interface: scanning probe microscopy reveals.- C-H activation as a generic route for on-surface synthesis of complex macromolecules.- Dehydrogenative and dehalogenative homocoupling reactions of C-X groups on metal surfaces.- On-surface Ullmann reaction for the synthesis of macrocycles and polymers.- Bottom-up fabrication of atomically precise graphene nanoribbons.- Aryl-aryl covalent coupling on rutile TiO2 surfaces.- On-surface synthesis of 2D networks: from graphene-like to graphyne-like networks.- Cu- and Pd-catalyzed on-surface coupling reactions.- nc-AFM to Address Long-Standing Chemical Challenges.
