Heterocycles from Carbenes and Nitrenes : Methods, Reactions and Synthetic Applications (Topics in Heterocyclic Chemistry) （2023）

Doyle, Michael P. (EDT)/ Xu, Xinfang (EDT)

Springer International Publishing AG（2024/08発売）

• 製本 Paperback:紙装版/ペーパーバック版／ページ数 377 p.
• 言語 ENG
• 商品コード 9783031367373

Full Description

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.

Contents

Photo-induced Carbene Transformations to Heterocycles.- Heterocycles from Onium Ylides.- Heterocycles from Sulfur Ylides.- Heterocycles from Cascade Reactions via Carbene gem-difunctionalization.- Cyclopropanation of Heterocycles.- Heterocycles from Cycloaddition Reaction.- Alkynes as Carbene Precursors for the Synthesis of Heterocycles.- Heterocycles from Donor/Donor Carbenes.- Heterocycles by Nitrene Transfer Reactions.