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Full Description
The biggest change in the years since the first edition is the proliferation of computational chemistry programs that calculate molecular properties. McQuarrie presents step-by-step SCF calculations of a helium atom and a hydrogen molecule, in addition to including the Hartree-Fock method and post-Hartree-Fock methods.
Contents
The Dawn of Quantum Theory.- The Classical Wave Equation.- The Schroedinger Equation and a Particle in a Box.- The Postulates and General Principles of Quantum Mechanics.- The Harmonic Oscillator and Vibrational Spectroscopy.- The Rigid Rotator and Rotational Spectroscopy.- The Hydrogen Atom.- Approximation Methods.- Many-Electron Atoms.- The Chemical Bond: One-and-Two-Electron Molecules.- Qualitative Theory of Chemical Bonding.- Appendices.- Solutions of Problems.- Index.