Structure and Rheology of Molten Polymers : From Structure to Flow Behavior and Back Again (2ND)

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Structure and Rheology of Molten Polymers : From Structure to Flow Behavior and Back Again (2ND)

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  • 製本 Hardcover:ハードカバー版/ページ数 592 p.
  • 言語 ENG
  • 商品コード 9781569906118
  • DDC分類 620.192

Full Description

Recent advances in polymer science have made it possible to relate quantitatively molecular structure to rheological behavior. At the same time, new methods of synthesis and characterization allow the preparation and structural verification of samples having a range of branched polymeric structures. This book unites this knowledge to enable production of polymers with prescribed processability and end-product properties.

Methods of polymer synthesis and characterization are described, starting from fundamentals. The foundations of linear viscoelasticity are introduced, and then the linear behavior of entangled polymers is described in detail. This is followed by a discussion of the molecular modeling of linear behavior. Tube models for both linear and branched polymers are presented. The final two chapters deal with nonlinear rheological behavior and tube models to describe nonlinearity.

In this second edition, each chapter has been significantly rewritten to account for recent advances in experimental methods and theoretical modeling. It includes new and updated material on developments in polymer synthesis and characterization, computational algorithms for linear and nonlinear rheology prediction, measurement of nonlinear viscoelasticity, entanglement detection algorithms in molecular dynamics, nonlinear constitutive equations, and instabilities.

Contents

Introduction
Structure of Polymers
Polymerization Reactions and Processes
Linear Viscoelasticity--Fundamentals
Linear Viscoelasticity--Behavior of Molten Polymers
Tube Models for Linear Polymers--Fundamentals
Tube Models for Linear Polymers--Advanced Topics
Determination of Molecular Weight Distribution Using Rheology
Tube Models for Branched Polymers
Nonlinear Viscoelasticity
Tube Models for Nonlinear Viscoelasticity of Linear and Branched Polymers