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2D NANOMATERIALS The book provides a comprehensive overview of the synthesis, modification, characterization, and application of 2D nanomaterials.
In recent years, 2D nanomaterials have emerged as a remarkable cornerstone in the field of advanced materials research, with their unique properties and versatile applications captivating the attention of scientists and engineers worldwide. This book is a testament to the ever-growing interest and importance of 2D nanomaterials in the realm of materials science, nanotechnology, pharmaceuticals, and a myriad of engineering specializations.
The book is structured into three sections, each delving into different aspects of 2D nanomaterials. The first section explores the synthesis of these materials, providing an overview of both top-down and bottom-up strategies. Understanding the methods by which these materials can be synthesized is crucial for advancing their potential applications. Additionally, this section details the structural characterization of 2D nanomaterials, shedding light on their intricate compositions and properties. The second section examines the diverse characteristics exhibited by 2D nanomaterials. From their magnetic and mechanical properties to their electrical, plasmonic, and optical behaviors, these materials possess an array of intriguing attributes that make them highly attractive for a wide range of applications. This section of the book provides a comprehensive understanding of these properties, enabling readers to appreciate the unique potential of 2D nanomaterials. The final section focuses on the applications of 2D nanomaterials, highlighting their use in various fields such as energy, water purification, biomedical applications, multimodal tumor therapy, and supercapacitor technology.
Contents
Preface xvii
Part I: Synthesis of 2D Nanomaterials 1
1 Top-Down Strategies Synthesis of 2D Nanomaterial 3
Pranjyan Dash and Pradeep Kumar Panda
1.1 Introduction 3
1.2 Top-Down Strategy Synthesis Method 5
1.3 Laser Ablation 10
1.4 Characterizations and Toxicity of 2D Nanomaterials 11
1.5 Conclusions 12
2 Bottom-Up Strategies for Synthesis of 2D Nanomaterial 17
Nibedita Nath, Subhendu Chakroborty and Anita Routaray
2.1 Introduction 17
2.2 Types of 2D Nanomaterial 18
2.3 Synthesis Strategies 21
2.4 Bottom-Up Strategies for Synthesis of 2D Nanomaterial 26
2.5 Conclusion and Outlook 32
3 Unveiling the Intricacies: Characterization Techniques for 2D Nanomaterials 43
Siba Soren, Subhendu Chakroborty, Rudra N. Purusottam and Amiya Ranjan Panda
3.1 Introduction 44
3.2 Characterization Techniques 45
3.3 Conclusion 53
Part II: Properties of 2D Nanomaterials 59
4 Crystal Structure, Magnetic and Mechanical Properties of 2D Nanomaterials 61
Nandini Roy
4.1 Introduction 62
4.2 Structure of 2D Materials 62
4.2.1 Graphene 62
4.3 Magnetic 2D Materials 65
4.4 Origin of Magnetization in 2D Materials 65
4.5 Mechanical Properties of 2D Nanomaterials 66
4.6 Conclusion 68
5 Electrical, Plasmonic, and Optical Properties of 2D Nanomaterials 73
Ankita Subhrasmita Gadtya and Srikanta Moharana
5.1 Introduction 74
5.2 Overview of Two-Dimensional Nanomaterials (2D NMs) 77
5.3 Electrical Properties of 2D NMs 80
5.4 Optical Properties of 2D NMs 84
5.5 Plasmonic Properties of 2D NMs 85
5.6 Recent Applications of 2D NMs 87
5.7 Challenges and Prospective 93
5.8 Conclusion 93
Part III: Application of 2D Nanomaterials 103
6 Challenges Surrounding 2D Nanomaterials and Their Application to Photocatalytic Industrial Wastewater Treatment 105
Anchit Modi and N. K. Gaur
6.1 Introduction 106
6.2 Photocatalysis for Industrial Wastewater Treatment 107
6.3 2D Nanomaterials in Photocatalysis 110
6.4 Challenges in Utilizing 2D Nanomaterials for Photocatalytic Wastewater Treatment 112
6.5 Strategies to Overcome Challenges 113
6.6 Case Studies and Applications 114
6.7 Conclusion 116
7 Application of 2D Nanomaterials for Energy Storage 121
Tulasi Barik and Subhendu Chakroborty
7.1 Introduction 121
7.2 2D Nanomaterials for Application of Lithium Ion Batteries 122
7.3 Application of 2D Nanomaterials in Sodium Ion Batteries 129
7.4 Application of 2D Nanomaterials in Potassium Ion Batteries 134
7.5 Applications of 2D Nanomaterials in Supercapacitors 137
8 Innovation in Photoinduced Antibacterial 2D Nanomaterials 155
Zubaid ul Khazir Rather, Shabnam Kawoosa, Gulam Nabi Yatoo, Mohd Asif Hajam, Sajad Ahmed Bhat and Javid Ahmed Banday
8.1 Introduction 156
8.2 Antibacterial Applications Based on Graphene-Induced Photostimulation 159
8.3 Antibacterial Mechanisms of Graphene-Based Family 168
8.4 Conclusion 172
9 2D Nanomaterials for Drug Delivery System 185
Syed Muzammil Munawar, Dhandayuthabani Rajendiran and Kaleel Basha Sabjan
9.1 Introduction 186
9.2 2D Material Biosynthesis 190
9.3 Encapsulation of 2D Materials 192
9.4 Hydrogel Encapsulation--2D Materials 193
9.5 2D Material Encapsulation--Liposomes 194
9.6 2D Supply Encapsulation--Micelle 195
9.7 Stimuli Responsive 2D Material SDDSs--Classification 195
9.8 Light-Sensitive SDDSs 196
9.9 Magnetic Field-Responsive SDDSs 196
9.10 Various Response Exhibits Diverse--Advantages/ Disadvantages 197
9.11 2D Material SDDS Therapy--Cancer 197
9.12 Antibacterial 198
9.13 Orthopedic 200
9.14 Diabetes Mellitus 200
9.15 2D Materials in Intelligent Drug Delivery System--Advantages 201
9.16 Disadvantages 201
9.17 Conclusion and Future Perspective 202
10 New Technology 2D Nanomaterials for Neural Tissue Engineering 209
Banti Baishya, Saurav Paul, Hillol Das, Utsab Singha and Dipyaman Mohanta
10.1 Introduction 210
10.2 Regeneration of Tissue and Organ Repair in Nature 211
10.3 Nanotechnology and Neural Tissue Engineering 214
10.4 2D Nanomaterials for Tissue Engineering Application 218
10.5 2D Nanomaterials and Peripheral Nerve Engineering 224
10.6 Application of 2D Nanomaterials in Spinal Cord Repair 231
10.7 2D Nanomaterials for Drug/Gene Delivery 233
10.8 Challenges and Prospects 234
11 Theranostic Approach of 2D Nanomaterials in Breast Cancer 241
Pravati Panda, Subhendu Chakroborty and Kaushik Pal
11.1 Introduction 242
11.2 Applications 243
12 2D Nanomaterials for Photocatalytic Hydrogen Production 263
Grandprix T. M. Kadja, St Mardiana and Arxhel S. F. Nanda
12.1 Introduction 264
12.2 Basics of Photocatalytic Hydrogen Production 265
12.3 2D Nanomaterials for Photocatalytic Hydrogen Production 267
12.4 Enhancing the Photocatalytic Performance 276
12.5 Conclusion and Outlook 280
13 Supercapacitor Based on 2D Nanomaterials and Their Hybrid 289
Anupam Kumar and Arun Rathore
13.1 Introduction 290
13.2 Structure Design of 2D Nanomaterial-Based Supercapacitors 297
13.3 2D Nanomaterials for Supercapacitor Technology 301
13.4 Conclusions 307
14 2D Nanomaterials Based for Electrocatalytic Application 315
Anchit Modi, D. K. Gupta, Jitendra Malviya and N. K. Gaur
14.1 Introduction 316
14.2 Types of 2D Nanomaterials 318
14.3 Electrocatalytic Reactions Enabled by 2D Nanomaterials 320
14.4 Challenges and Future Perspectives 325
14.5 Conclusion 327
15 Engineering 2D Nanomaterials for Biomedical Applications 333
Swaati Sharma, Hardeep Kaur, Mansi Thakur and Shinar Athwal
15.1 Introduction 334
15.2 Synthesis of Nanomaterials 337
15.3 Nanomaterials for Cancer Treatment 338
15.4 Difference of 2D Materials from Bulk Materials 339
15.5 2DNMS for Next-Generation Quantum and Electronic Devices 352
15.6 Functionalized Hybridization of 2D Nanomaterials 352
16 The Potential Applications of 2D Nanomaterials for Water Purification 361
Hardeep Kaur, Swaati Sharma, Shinar Athwal, Mansi Thakur, Meenakshi Verma and Vishal Mutreja
16.1 Introduction 362
16.2 Contaminants Present in Water 363
16.3 2D Nanomaterial-Based Water Purification Membranes 364
16.4 Solar Desalination Membrane 365
16.5 Filtration Membrane 367
16.6 Properties of Widely Used 2DM for Water Purification 369
16.7 Synthesis of 2DM 376
16.8 Adsorption of Contaminants From Water 382
16.9 Photocatalytic Purification of Water 387
16.10 Conclusion and Future Prospects 389
17 Insights into the Exciton Dynamics of Functionalized 2D Nanomaterials for Robust Photoelectrochemical Sensing Applications 397
Dipyaman Mohanta, Koushik Barman, Abhinandan Mahanta, Bishal Bhuyan and Arpita Paul Chowdhury
17.1 Introduction 398
17.2 Basic Theory and Working Principle of Photoelectrochemical Sensing 400
17.3 Experimental Setup of Photoelectrochemical Cell 401
17.4 Importance of Photoactive Material in Photoelectrochemical Sensing 402
17.5 2D Nanomaterials in Photoelectrochemical Sensing 403
17.6 Current Challenges and Future Prospects 407
17.7 Conclusion 408
18 Fabrication of 2D Nanomaterials-Based Biosensor 415
Arpita Paul Chowdhury, M. Dinamani and K. S. Anantharaju
18.1 Introduction 415
18.2 2D Nanomaterial Synthesis Strategies 417
18.3 Role of 2D Materials in Biosensor 418
18.4 Conclusions and Future Prospective 426
19 Transition Metal Dichalcogenide (TMD)-Based 2D Nanomaterials for Various Kinds of Rechargeable Batteries 435
Periyakaruppan Karuppasamy and Varatharaj Rajapanian
19.1 Introduction 436
19.2 Synthesis of 2D-TMDCs 440
19.3 Applications of 2D-Transition Metal Di-Chalcogenides (2D-TMDCs) in Various Categories of Rechargeable Batteries 443
19.4 Conclusion 461
20 Effect of 2D Nanomaterial Addition to Performance and Emission Characteristics of Diesel Engine 475
Geetesh Goga and M. V. B. Unnamatla
20.1 Introduction 476
20.2 Performance Characteristics 477
20.3 Emission Characteristics 481
20.4 Conclusion 484
References 485
Index 489
