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Full Description
The ultimate resource in organoboron chemistry
Professor Mark Gandelman and his colleagues delve deeply into the theory, structure, analysis, synthesis, and reactions of organoboron chemistry in The Chemistry of Organoboron Compounds. Organoborons are used heavily as highly efficient reagents in many reactions, including cross-coupling and radical reactions. The highly regarded authors have tied together organic-chemical and physico-chemical knowledge usually unavailable from a single source. The book focuses on the use of completely biodegradable "green" reagents, as opposed to environmentally hazardous heavy metal catalysts.
The Chemistry of Organoboron Compounds delivers comprehensive and complete information on:
The behavior of organoboron compounds
The use of organoboron compounds in organic synthesis
The commercial applications of organoboron compounds
As a volume in the celebrated Patai book series, The Chemistry of Organoboron Compounds includes all the features that readers of that series are used to enjoying, including a comprehensive index at the back of the book.
Contents
1. Catalytic asymmetric Swuzuki-Miyaura couplings 1
F. Wieland Goetzke, Lucy van Dijk, and Stephen P. Fletcher
2. Metal-catalyzed hydroboration reactions of alkyne and subsequent asymmetric transformation 55
Jun Guo and Zhan Lu
3. Aspects of the chemical energetics of species with carbon-boron bonds and related compounds 91
Suzanne W. Slayden and Joel F. Liebman
4. Electrochemistry of organoboron compounds 115
Toshio Fuchigami and Shinsuke Inagi
5. The chemistry of organotrifluoroborates 141
Livia N. Cavalcanti, Júlia C. C. V. Bento, and Gary A. Molander
6. The chemistry of organoboron species: classification and basic properties 221
Cory Williams, Mario Luis, Ivan Lopez, and Adiel Coca
7. Recent advances in the stereoselective additions of allylic boronates to carbonyl compounds 243
Helen A. Clement and Dennis G. Hall
8. Synthesis and reactivity of bora- and borata-benzenes 329
Ivo Krummenacher, Julia K. Schuster, and Holger Braunschweig
9. Boron-doped polycyclic aromatic hydrocarbons (B-PAHs): synthesis, properties, and applications 367
María M. Lorenzo-García, Francesco Fasano, and Davide Bonifazi
10. The chemistry of multibonded organoboron compounds 461
Marc Devillard and Gilles Alcaraz
11. 1,2-Metallate rearrangement of boron derivatives 561
Joseph M. Bateman and Varinder K. Aggarwal
12. Photochemical transformations involving organoboron 657
Soren K. Mellerup and SuningWang
13. Synthesis and reactivity of 1,1- and 1,2-bisboronate species 701
Rajender Nallagonda, Nivesh Kumar, Rajasekhar Reddy Reddy, Israa Shioukhi, Hila Sagi, and Ahmad Masarwa
14. Copper-catalyzed addition of diboron species 773
Alejandro Parra, Laura Trulli, and Mariola Tortosa
15. The chemistry of boron enolate: synthesis and reactivity 855
Atsushi Abiko
16. Boron-mediated radical reactions 931
Emy André-Joyaux, Lars Gnägi, Manuel Gnägi-Lux, Camilo Andrés Melendez Becerra, Valentin Soulard, Nicholas D. C. Tappin, and Philippe Renaud
17. Boron-based frustrated Lewis pairs in hydrogenation catalysis 1033
Douglas W. Stephan
18. Boron-based frustrated Lewis pairs in organic transformations 1061
Roman Dobrovetsky
Subject index 1109
