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Full Description
The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues.
The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here.
As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Contents
Part 1
1 An introduction to the consequences of spin and bond strength in the chemistry of diatomic oxygen, peroxides, and related species 1
Alexander Greer
Alexandru T. Balaban
Joel F. Liebman
2 Applications of endoperoxides derived from acenes and singlet oxygen 21
Werner Fudickar
Torsten Linker
3 1,1-Dihydroperoxides 87
Chris Schwartz
Patrick H. Dussault
4 Peroxide intermediates of oxidation processes: Organic trioxides 125
Sergey L. Khursan
5 Organic tetroxides and mechanism of peroxy radical recombination 197
Sergey L. Khursan
6 1,2-Dioxatrisulfane (thiaperoxide) intermediates in type I and II photooxygenation reactions 231
Edward L. Clennan
7 Sulfoxylic and thiosulfurous acids and their dialkoxy derivatives 265
Sergei V. Makarov
Anna S. Makarova
Radu Silaghi-Dumitrescu
8 Reactions of metal complexes with singlet oxygen 307
Matthias Selke
9 The chemistry of nitroso oxides 357
Ekaterina M. Chainikova
Sergey L. Khursan
Rustam L. Safiullin
10 Single-molecule reactive oxygen species detection in photocatalytic reactions 421
Takashi Tachikawa
Tetsuro Majima
11 Reactions of peroxides on solid surfaces 437
Rossella Mello
Maria Elena Gonzalez Nunez
12 Peroxide explosives 503
Thomas M. Klapotke
Thomas Wloka
13 Gas-phase ion chemistry of organic peroxides 531
Shuji Kato
Stephen J. Blanksby
14 Quantum chemical studies of carbonyl oxide chemistry in combustion and in the lower atmosphere 585
Keith T. Kuwata
15 Computational treatments of peroxy radicals in combustion and atmospheric reactions 633
Keith T. Kuwata
16 Heteroatom-substituted dioxetanes and their emerging biomedical applications 683
Gregory Nkepang
Youngjae You
17 The use of hydrogen peroxide for disinfection and sterilization applications 713
Gerald McDonnell
18 Generation and reactivity of lipid hydroperoxides in biological systems 747
Albert W. Girotti
Witold Korytowski
19 [ 18O]-Peroxides: Synthesis and biological applications 769
Paolo Di Mascio
Sayuri Miyamoto
Marisa H. G. Medeiros
Glaucia R. Martinez
Jean Cadet
20 Copper peroxide bioinorganic chemistry: From metalloenzymes to bioinspired synthetic systems 805
Isaac Garcia-Bosch
Kenneth D. Karlin
Subject Index 857
