Rotational Spectroscopy of Diatomic Molecules (Cambridge Molecular Science)

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Rotational Spectroscopy of Diatomic Molecules (Cambridge Molecular Science)

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  • 製本 Hardcover:ハードカバー版/ページ数 1013 p.
  • 言語 ENG
  • 商品コード 9780521810098
  • DDC分類 539.60287

Full Description


Written to be the definitive text on the rotational spectroscopy of diatomic molecules, this book develops the theory behind the energy levels of diatomic molecules and then summarises the many experimental methods used to study their spectra in the gaseous state. After a general introduction, the methods used to separate nuclear and electronic motions are described. Brown and Carrington then show how the fundamental Dirac and Breit equations may be developed to provide comprehensive descriptions of the kinetic and potential energy terms which govern the behaviour of the electrons. One chapter is devoted solely to angular momentum theory and another describes the development of the so-called effective Hamiltonians used to analyse and understand the experimental spectra of diatomic molecules. The remainder of the book concentrates on experimental methods. This book will be of interest to graduate students and researchers interested in the rotational spectroscopy of diatomic molecules.

Table of Contents

1. General introduction
2. The separation of nuclear and electronic
motion
3. The electronic hamiltonian
4. Interactions arising from nuclear magnetic
and electric moments
5. Angular momentum theory and spherical tensor
algebra
6. Electronic and vibrational states
7. Derivation of the effective hamiltonian
8. Molecular beam magnetic and electric
resonance
9. Microwave and far-infrared magnetic resonance
10. Pure rotational spectroscopy
11. Double resonance spectroscopy
Appendices.