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Full Description
Written for theoretical and chemical physicists, this text emphasizes theory rather than mathematical calculations. It presents the quantum theory of the electronic structure of atoms and explains what that structure is like by presenting the main results of the theory. It is novel in its approach in that it presents a systematic, critical evaluation of some numerical results that have been obtained by Hartree-Fock models. It also treats relativistic atomic theory on a par with the non-relativistic.
Contents
THE HARTREE-FOCK MODEL. Single-Determinantal Hartree-Fock Theory. Atoms with Incomplete Groups. Relativistic Hartree-Fock Theory. A Discussion of Some Representative Hartree-Fock Results. VALENCE-ELECTRON THEORIES. Hartree-Fock Theory for Valence Electrons. Effective Hamiltonian Theory for One Valence Electron. Effective Hamiltonians for Several Valence Electrons. Relativistic Effective Hamiltonian Theory. Appendices. References. Index.
