有機化合物のスペクトルによる同定法（第７版） Spectrometric Identification of Organic Compounds （7TH）

Silverstein, Robert M./ Webster, Francis X./ Kiemle, David J.

John Wiley & Sons Inc（2005/01発売）

• 製本 Hardcover:ハードカバー版／ページ数 502 p.
• 言語 ENG
• 商品コード 9780471393627
• DDC分類 543.5

基本説明

The Classic in its field. Provides a thorough introduction to the three areas of spectrometry; mass spectrometry, infrared spectrometry, and nulear magnetic resonance spectrometry.

Full Description

Originally published in 1962, this was the first book to explore teh identification of organic compounds using spectroscopy. It provides a thorough introduction to the three areas of spectrometry most widely used in spectrometric identification: mass spectrometry, infrared spectrometry, and nuclear magnetic resonance spectrometry. A how-to, hands-on teaching manual with considerably expanded NMR coverage--NMR spectra can now be intrepreted in exquisite detail. This book: Uses a problem-solving approach with extensive reference charts and tables. Offers an extensive set of real-data problems offers a challenge to the practicing chemist

Contents

Chapter 1. Mass Spectrometry. 1.1 Introduction. 1.2 Instrumentation. 1.3 Ionization Methods. 1.4 Mass Analyzers. 1.5 Interpretation of El Mass Spectra. 1.6 Mass Spectra of Some Chemical Classes. Chapter 2. Infrared Spectrometry. 2.1 Introduction. 2.2 Theory. 2.3 Instrumentation. 2.4 Sample Handling. 2.5 Interpretations of Spectra. 2.6 Characteristic Group Absorption of Organic Molecules. Chapter 3. Proton Magnetic Resonance Spectrometry. 3.1 Introduction. 3.2 Theory. 3.3 Instrumentation and Sample Handling. 3.4 Chemical Shift. 3.5 Spin Coupling, Multiplets, Spin Systems. 3.6 Protons on Oxygen, Nitrogen, and Sulfur Atoms. Exchangeable Protons. 3.7 Coupling of Protons to Other Important Nuclei (¹⁹F, E, ³¹P, ²⁹Si, and ¹³C. 3.8 Chemical Shift Equivalence. 3.9 Magnetic Equivalence (Spin-Coupling Equivalence). 3.10 AMX, ABX, and ABC Rigid Systems with Three Coupling Constants. 3.11 Confirmationally Mobile, Open-Chain Systems. Virtual Coupling. 3.12 Chirality. 3.13 Vicinal and Geminal Coupling. 3.14 Low-Range Coupling. 3.15 Selective Spin Decoupling. Double Resonance. 3.16 Nuclear Overhauser Effect, Difference Spectrometry, 1H 1H Proximity Through Space. Chapter 4. Carbon-13 NMR Spectrometry. 4.1 Introduction. 4.2 Theory. 4.3 Interpretation of a Simple ¹³C Spectrum: Diethyl Phthalate. 4.4 Quantitative ¹³C Analysis. 4.5 Chemical Shift Equivalence. 4.6 DEPT. 4.7 Chemical Classes and Chemical Shifts. Chapter 5. Correlation NMR Spectrometry; 2-D NMR. 5.1 Introduction. 5.2 Theory. 5.3 Correlation Spectrometry. 5.4 Ipsenol: ¹H-¹H COSY. 5.5 Caryophyllene Oxide. 5.6 ¹³C-¹³C Correlations: Inadequate. 5.7 Lactose. 5.8 Relayed Coherence Transfer: TOCSY. 5.9 HMQC - TOCSY. 5.10 ROESY. 5.11 VGSE. 5.12 Gradient Field NMR. Chapter 6. NMR Spectrometry of Other Important Spin 1/2 Nuclei. 6.1 Introduction. 6.2 ¹⁵N Nuclear Magnetic Resonance. 6.3 ¹⁹F Nuclear Magnetic Resonance. 6.4 ²⁹Si Nuclear Magnetic Resonance. 6.5 ³¹P Nuclear Magnetic Resonance. 6.6 Conclusion. Chapter 7. Solved Problems. 7.1 Introduction. Chapter 8. Assigned Problems. 8.1 Introduction.