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基本説明
Detailed information on 200 reagents to be used for the functionalization of C-H bonds in the carbon backbone of organic molecules.
Full Description
A concise and informative collection of articles on the synthesis of organic, biological and medicinal materials. Key Features:* Detailed information on 200 reagents to be used for the functionalization of C-H bonds in the carbon backbone of organic molecules* A systematic approach to the use of organometallic compounds in organic synthesis* Articles will stress chemical aspects such as yield, conversion, specifity [enantio, stereo, regio, chemo], and where applicable, catalyst loading/turnover
Contents
Preface ixIntroduction 1Recent Review Articles and Monographs 9Allyl Triflone 112-Amino-3-Picoline 121,2-Benziodoxoyl-3(1H)-one Derivatives 172,2-Bis{lcub}[2-[4(S)-tert-butyl-1,3-oxazinyl]{rcub} propane 20Bis(cyclopentadienyl)methylzirconium Tetraphenylborate-Tetrahydrofuran 26Bis[dimethyl([micro]-dimethyl sulfide)-platinum(II)] 28N-Bromosuccinimide 30Carbon Tetrabromide 41Carbon Tetraiodide 434-(4-Chlorophenyl)-3-hydroxy-2(3H) thiazolethione 45Chromium(VI) Oxide 48Chromium(VI) Oxide-3,5-Dimethylpyrazole 53Chromium(VI) Oxide-Dipyridine 54Chromyl Acetate 57Copper(I){lcub}Hydrotris(3,4,5-tribromo)pyrazolylborate{rcub}(acetonitrile) 60Copper(I),[Hydrotris[3-(2,4,6-trimethylphenyl)-1H-pyrazolato-N[subscript 1]] borato(1-)-N[subscript 2],N[prime][subscript 2]N[tprime][subscript 2] 63Copper(II) Acetate 64Copper(II) Chloride 71Di-(-)-(1R,2S)-2-phenyl-l-cyclohexyl Diazenedicarboxylate 79(Diacetoxyiodo)benzene 80Dibenzoyl Peroxide 89Di-t-butyl Chromate 99Di-t-butyl Peroxide 102Dimethyl Diazomalonate 107Dimethyldioxirane 113Dipotassium Tetrachloroplatinate(II) 119Dirhodium(II) bis-{lcub}1,3-[N,N[prime]-di(4-Dodecyl-Benzenesulfonyl)-(2S,2[prime] S),(5R,5[prime] R)-5,5[prime]-Prolinate]Benzene{rcub} 120Dirhodium(II) Tetra(caprolactamate) 122Dirhodium(II) Tetrakis(perfluorobutyrate) 124Dirhodium(II) Tetrakis(trifluoroacetate) 126Dirhodium(II) Tetrakis(triphenylacetate) 129Dirhodium(II) Tetraacetamide 132Dirhodium(II) Tetraacetate 134Dirhodium(II) Tetrakis[Alkyl 2-oxaazetidine-4(S)-carboxylate] 144Dirhodium(II) Tetrakis[1-[[(4-dodecylphenyl]sulfonyl]-prolinate] 146Dirhodium(II) Tetrakis[methyl 1-(3-phenylpropanoyl)-2-oxaimidazolinidinecarboxylate] 154Dirhodium(II) Tetrakis [methyl 2-oxapyrrolidine-carboxylate] 157Dirhodium(II) Tetrakis [methyl 2-oxooxazolidine-4(S)-carboxylate] 160Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate] 162Dirhodium(II) Tetraoctanoate 166Disodium Tetrachloroplatinate(II) 169Ethyl Azidoformate 171Gallium Trichloride 1811-Hydroxy-1,2-benziodoxol-3(1H)-one 187Hypofluorous Acid 190Hypofluorous Acid, Acetonitrile Complex 191Iridium(V) Pentahydrobis(isopropylphosphine) 197Iron(II) Bis(pyridine)bis(2-pyridinecarboxylato-N1,O[subscript 2]) 198Iron(II) Perchlorate 202Iron(II) Phthalocyanine 202Iron(II) 1,3,2-Benzodioxaborol-2-yldicarbonyl ([eta][superscript 5]-2,4-cyclopentadien-1-yl) 204Mercury(0) 207Methyl Phenyldiazoacetate 209Methyl(trifluoromethyl)dioxirane 214Oxaziridine, 3-Fluoro-3-(heptafluoropropyl)-2-(nonafluorobutyl) 221Palladium(II) Acetate 229Pinacol Diborane 253Pinacolborane 260Platinum(II) Chloride 263Rhenium(VII) Methyltrioxo 271Rhenium(VII) Aquamethyloxodiperoxy 276Rhenium(VII) Methyloxodiperoxy 283Rhodium(I) bis Cyclooctene Chloride Dimer 287Rhodium(I) Carbonyl(chloro)bis(triphenylphosphine) 293Rhodium(I) Chlorotris(triphenylphosphine) 303Ruthenium (0) Dodecacarbonyl, Triangulo 315Ruthenium(II) Dichlorotris(triphenylphosphine) 318Ruthenium(II), bis[N,N-bis-[(2-pyridyl-[kappa]N)methyl]-2-pyridinemethanamine-N1,N2] di-[micro]-chloride 322Ruthenium(III) Chloride 324Ruthenium(III) N,N[prime],N[Prime],-Trimethyl-1,4,7-triazacyclononane + Ruthenium(II) cis-diaquabis(6,6[prime]-dichloro-2,2[prime]-bipyridine)bistriflate 328Ruthenium(VIII) Oxide 331Selenium(IV) Oxide 341Silver(I) [tris[3,5-bis(trifluoromethyl)-1H-pyrazolato-N1]hydroborato(1-)-N2, N2[prime], N2[tprime]-tetrahydrofuran 343Triethylborane 347Trifluoromethyl Sulfonyl Ethynyl Benzene 362Triisopropylsilylethynyl Triflone 363Tungsten(II) Tricarbonyl(4,6-dimethyl-1,3,2-benzodioxaborol-2-yl)[(1,2,3,4,5,-[eta])-1,2,3.4,5-pentamethyl-2,4-cyclopentadien-l-yl) 364Tungstoboric Acid, Tetrakis(tetrabutylammonium) Salt 366Vanadium(VI) Dioxobis(pyrazine-2-carboxylate) Tetrabutylammonium 371Vanadium(V) Diaquaoxoperoxy (2-pyridinecarboxylate-[kappa]N1, [kappa]02) 375List of Contributors 379Reagent Formula Index 387Subject Index 391
