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Full Description
Materials Kinetics: Transport and Rate Phenomena, Second Edition provides readers with a clear understanding of how physical-chemical principles are applied to fundamental kinetic processes. The book integrates advanced concepts with foundational knowledge and cutting-edge computational approaches, demonstrating how diffusion, morphological evolution, viscosity, relaxation, and other kinetic phenomena can be applied to practical materials design problems across all classes of materials. Thermodynamics, Fick's law, dislocation and interfacial motion, kinetics of phase separation, molecular dynamics, energy landscapes, and Monte Carlo simulation techniques are each covered. This second edition also features brand new chapters on sintering, topological constraint theory, ab initio molecular dynamics, thermal conduction, and electrical conduction. All preexisting chapters have been revised and updated to include new exercises and topics covered have been expanded to include examples of multicomponent diffusion, particle jump frequency, diffusion along dislocations, modeling of grain boundary diffusion, applications of phase-field modeling, applications of diffuse interface theory, and much more.
Contents
1. Thermodynamics vs. Kinetics
2. Irreversible Thermodynamics
3. Fick's Laws of Diffusion
4. Analytical Solutions of the Diffusion Equation
5. Multicomponent Diffusion
6. Numerical Solutions of the Diffusion Equation
7. Atomic Models for Diffusion
8. Diffusion in Crystals
9. Diffusion in Polycrystalline Materials
10. Motion of Dislocations and Interfaces
11. Morphological Evolution in Polycrystalline Materials
12. Sintering
13. Diffusion in Polymers and Glasses
14. Kinetics of Phase Separation
15. Nucleation and Crystallization
16. Advanced Nucleation Theories
17. Viscosity of Liquids
18. Nonequilibrium Viscosity and the Glass Transition
19. Topological Constraint Theory
20. Energy Landscapes
21. Broken Ergodicity
22. Master Equations
23. Relaxation of Glasses and Polymers
24. Molecular Dynamics
25. Monte Carlo Techniques
26. Ab Initio Molecular Dynamics
27. Fluctuations in Condensed Matter
28. Chemical Reaction Kinetics
29. Thermal Conduction
30. Electrical Conduction