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Full Description
Ideal for any practicing or future organic chemist or biochemist, Organic Structural Spectroscopy presents the fundamentals of all four principal spectroscopic methods: nuclear magnetic resonance spectroscopy, mass spectrometry, infrared spectroscopy, and ultraviolet-visible spectroscopy. Each topic is examined in depth by an experienced author who is a practicing expert in that area. The material begins at the most elementary level and progresses to the level required for organic research. Among many other enhancements, the Second Edition offers an entirely new discussion of mass spectrometry, with comprehensive coverage of new ionization and fragmentation methods, and treatment of NMR from the basics to advanced 2D methods.
Contents
Chapter 2 Introduction2-1 Magnetic Properties of Nuclei2-2 The Chemical Shift2-3 Excitation and Relaxation2-4 Pulsed Experiments2-5 The Coupling Constant2-6 Quantification and Complex Splitting2-7 Commonly Studied Nuclides2-8 Dynamic Effects2-9 Spectra of Solids2-10 Experimental MethodsProblemsTips on Solving NMR ProblemsBibliographyPart I NUCLEAR MAGNETIC RESONANCE SPECTROSCOPYChapter 1 Introduction1-1 The Spectroscopic Approach to Structure Determination1-2 Contributions of Different Forms of Spectroscopy1-3 The Electromagnetic Spectrum1-4 Molecular Weight and Molecular Formula1-5 Structural Isomers and StereoisomersProblemsChapter 3 The Chemical Shift3-1 Factors That Influence Proton Shifts3-2 Proton Chemical Shifts and Structure3-3 Medium and Isotope Effects3-4 Factors That Influence Carbon Shirts3-5 Carbon Chemical Shifts and Structure3-6 Tables of Chemical ShiftsProblemsFurther Tips on Solving NMR ProblemsBibliographyChapter 4 The Coupling Constant4-1 First-Order Spectra4-2 Chemical and Magnetic Equivalence4-3 Signs and Mechanisms4-4 Couplings over One Bond4-5 Geminal Couplings4-6 Vicinal Couplings4-7 Long-Range Couplings4-8 Spectral Analysis4-9 Second-Order Spectra4-10 Tables of Coupling ConstantsProblemsBibliographyChapter 5 Further Topics in One-Dimensional NMR5-1 Spin-Lattice and Spin-Spin Relaxation5-2 Reactions on the NMR Time Scale5-3 Multiple Resonance5-4 The Nuclear Overhauser Effect5-5 Spectral Editing5-6 Sensitivity Enhancement5-7 Carbon Connectivity5-8 Phase Cycling, Composite Pulses, and Shaped PulsesProblemsBibliographyChapter 6 Two-Dimensional NMR6-1 Proton-Proton Correlation Through Coupling6-2 Proton-Heteronucleus Correlation6-3 Proton-Proton Correlation Through Space or Chemical Exchange6-4 Carbon-Carbon Correlation6-5 Higher Dimensions6-6 Pulsed Field Gradients6-7 Summary of Two-Dimensional MethodsProblemsBibliographyPart II MASS SPECTROMETRYChapter 7 Instrumentation and Theory7-1 Introduction7-2 Ionization Methods7-3 Mass Analysis7-4 Sample PreparationChapter 8 Ion Activation and Fragmentation8-1 Basic Principles8-2 Methods and Energetics 8-3 Functional GroupsChapter 9 Structural Analysis9-1 Molecular Weights9-2 Molecular Formula9-3 Structures from Fragmentation Patterns9-4 PolymersChapter 10 Quantitative Applications10-1 Quantification of Analytes10-2 ThermochemistryPart III VIBRATIONAL SPECTROSCOPYChapter 11 Introduction11-1 Introduction11-2 Vibrations of Molecules11-3 Infrared and Raman Spectra11-4 Units and Notation11-5 Infrared Spectra: Dispersive and Fourier Transform11-6 Sampling Methods for Infrared Transmission Spectra11-7 Raman Spectroscopy11-8 Raman Sampling Methods11-9 Depolarization Measurements11-10 Infrared Reflection SpectroscopyProblemsBibliographyChapter 12 Group Frequencies12-1 Introduction12-2 Factors Affecting Group Frequencies12-3 Infrared Group Frequencies12-4 Raman Group Frequencies12-5 Preliminary Analysis12-6 The CH Stretching Region (3340-2700 cm-1)12-7 The Carbonyl Stretching Region (1850-1650 cm-1)12-8 Aromatic Compounds12-9 Compounds Containing Methyl Groups12-10 Compounds Containing Methylene Groups12-11 Unsaturated Compounds12-12 Compounds Containing Oxygen12-13 Compounds Containing Nitrogen12-14 Compounds Containing Phosphorus and Sulfur12-15 Heterocyclic Compounds12-16 Compounds Containing Halogens12-17 Boron, Silicon, Tin, Lead, and Mercury Compounds12-18 Isotopically Labeled Compounds12-19 Using the Literature on Vibrational SpectroscopyProblemsBibliographyPart IV ELECTRONIC ABSORPTION SPECTROSCOPYChapter 13 Introduction and Experimental Methods13-1 Introduction13-2 Measurement of Ultraviolet-Visible Light Absorption13-3 Quantitative Measurements13-4 Electronic Transitions13-5 Experimental AspectsProblemsBibliographyChapter 14 Structural Analysis14-1 Isolated Chromophores14-2 Conjugated Chromophores14-3 Aromatic Compounds14-4 Important Naturally Occurring Chromophores14-5 The Woodward-Fieser Rules14-6 Steric Effects14-7 Solvent Effects and Dynamic Equilibria14-8 Hydrogen Bonding Studies14-9 Homoconjugation14-10 Charge Transfer Band14-11 Worked ProblemsProblemsBibliography
