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Full Description
Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials.
The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds.
Contents
1. The Cosmic Origin of Fluorine: An Astronomer's View on Fluorine Synthesis
2. The Fluorine Atom in Health Care and Agrochemical Applications: A Contribution to Life Science
3. Industrial Syntheses of Hydrohaloolefins and Related Products
4. Electrochemical Fluorination: A Powerful Tool for the Preparation of Organofluorine Compounds
5. Once Upon a Time Was the Langlois' Reagent: A "Sleeping Beauty”
6. Toward CF3S Group: From Trifluoromethylation of Sulfides to Direct Trifluoromethylthiolation
7. Nucleophilic Di- and Trifluoromethylation of CO and CN Bonds
8. Oxidative Trifluoromethylation and Trifluoromethylthiolation
9. Catalytic Enantioselective Fluorination
10. Development of Electrophilic Trifluoromethylating Reagents
11. New Nucleophilic Fluoroalkylations
12. Continuous Flow Selective Direct Fluorination Using Fluorine Gas
13. Synthesis of Fluorinated Nitrogen-Containing Compounds Through Superelectrophilic Activation in Superacid HF/SbF5
14. Visible Light-Induced (Per)fluoroalkylation by Photoredox Catalysis
15. Synthesis of Side Chain Fluorinated Amino Acids and Their Effects on the Properties of Peptides and Proteins
16. Ionic Liquids and Polymers for Battery and Fuel Cells
17. Strategic Incorporation of Fluorine for Drug Discovery and Development
18. Telomerization Reaction of 3,3,3-Trifluoropropene
19. High Oxidation States in Transition Metal Fluorides
20. Photochemical Syntheses of Fluorides in Liquid Anhydrous Hydrogen Fluoride
21. Sol-Gel Synthesis of Metal Fluorides: Reactivity and Mechanisms
22. Solution-Based Synthesis of Nano-Sized TiO2 Anatase in Fluorinating Media
23. Ionic Liquid Materials Based on Fluoroanions
24. Reactivity of Surface Fluorinated TiO2 and TiAl Particles
25. Chemical and Electrochemical Stability of Copper in Molten KF-2HF
