Description
A crucial overview of the cutting-edge in nanocarbon research and applications
In Synthesis and Applications of Nanocarbons, the distinguished authors have set out to discuss fundamental topics, synthetic approaches, materials challenges, and various applications of this rapidly developing technology. Nanocarbons have recently emerged as a promising material for chemical, energy, environmental, and medical applications because of their unique chemical properties and their rich surface chemistries. This book is the latest entry in the Wiley book series Nanocarbon Chemistry and Interfaces and seeks to comprehensively address many of the newly surfacing areas of controversy and development in the field.
This book introduces foundational concepts in nanocarbon technology, hybrids, and applications, while also covering the most recent and cutting-edge developments in this area of study.
Synthesis and Applications of Nanocarbons addresses new discoveries in the field, including:
· Nanodiamonds
· Onion-like carbons
· Carbon nanotubes
· Fullerenes
· Carbon dots
· Carbon fibers
· Graphene
· Aerographite
This book provides a transversal view of the various nanocarbon materials and hybrids and helps to share knowledge between the communities of each material and hybrid type.
Table of Contents
List of Contributors xi
Series Preface xiii
Preface xv
1 Properties of Carbon Bulk Materials: Graphite and Diamond 1
Kamatchi Jothiramalingam Sankaran and Ken Haenen
1.1 Introduction 1
1.2 Graphite 2
1.3 Diamond 7
1.4 Characterization of Graphite and Diamond 14
1.5 Properties of Graphite and Diamond 18
1.6 Applications of Graphite and Diamond 20
References 21
2 Endohedral and Exohedral Single-Layered Fullerenes 25
Diana M. Bobrowska and Marta E. Plonska-Brzezinska
2.1 Introduction 25
2.2 Structure and Physicochemical Properties of “Empty” Single-Layered Fullerenes 25
2.3 Structure and Physicochemical Properties of Endohedral Fullerenes 29
2.4 Functionalization and Application of Single-Layered Fullerenes 32
2.5 Summary 42
Acknowledgments 42
References 42
3 Spherical Onion-Like Carbons 63
Diana M. Bobrowska and Marta E. Plonska-Brzezinska
3.1 Introduction 63
3.2 Structure of Onion-Like Carbons and Their Physicochemical Properties 63
3.3 Covalent and Noncovalent Functionalization of OLCs 69
3.4 Doping of OLCs by Heteroatoms 82
3.5 Applications of OLCs 84
3.6 Summary 90
Acknowledgments 91
References 91
4 Carbon Nanotubes: Synthesis, Properties, and New Developments in Research 107
Marianna V. Kharlamova and Dominik Eder
4.1 Introduction 107
4.2 Atomic Structure of Carbon Nanotubes 108
4.3 Properties of Carbon Nanotubes 109
4.4 Synthesis of Carbon Nanotubes 111
4.5 Postsynthesis Treatments of Carbon Nanotubes 114
4.6 New Developments in Carbon Nanotube Research: Toward Controllable Properties of Nanotubes 117
4.7 Conclusions and Outlook 125
Acknowledgments 128
References 129
5 CNT Fiber-Based Hybrids: Synthesis, Characterization, and Applications in Energy Management 149
Moumita Rana, Cleis Santos, Alfonso Monreal-Bernal and Juan J. Vilatela
5.1 Introduction: What are CNT Fibers andWhy Do they Form Interesting Hybrids and Composites? 149
5.2 Hybridization with Metal Oxides 153
5.3 EDLC Introducing Pseudocapacitive Reactions 182
5.4 Capacitive Deionization 185
5.5 Battery Electrodes 189
5.6 Conclusions and Perspective 193
References 194
6 Advanced Materials Designed with Nanodiamonds: Synthesis and Applications 201
Jean-Charles Arnault
6.1 Introduction 201
6.2 Synthesis of Isolated Objects from ND 203
6.3 Decoration of Particles by ND, Core Shells with Diamond Shell 215
6.4 Conclusion and Perspectives 219
References 220
7 Chemical Functionalization of Nanodiamond for Nanobiomedicine 229
Naoki Komatsu
7.1 Introduction 229
7.2 ND for Fluorescent Cell Labeling 229
7.3 ND for MRI 235
7.4 ND for Gene Delivery 238
7.5 ND for Drug Delivery 241
7.6 Concluding Remarks 244
Acknowledgments 245
References 245
8 Nanocarbon Aerogels and Aerographite 247
Hubert Beisch and Bodo Fiedler
8.1 Introduction 247
8.2 Fabrication 247
8.3 Morphology 253
8.4 Properties 258
8.5 Modifications 267
8.6 Conclusion 270
References 271
9 Optoelectronic Properties of Nanocarbons and Nanocarbon Films 275
Cameron J. Shearer, LePing Yu and Joseph G. Shapter
9.1 Introduction 275
9.2 Nanocarbons 276
9.3 Fundamentals of Optical and Electronic Properties of Nanocarbons 280
9.4 Optoelectronic Properties of Nanocarbon Films 287
9.5 Summary and Outlook 289
References 290
Index 295
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