カルベン錯体：中間体から試薬へ Carbene Chemistry : From Fleeting Intermediates to Powerful Reagents

著者名：Bertrand, Guy

CRC Press（2002/05/14発売）

• 言語：ENG
• ISBN：9780824708313
• eISBN：9781135565824
• NDC分類：499.3

Description

Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.

Table of Contents

Matrix isolation of highly electrophilic carbenes; observing invisible carbenes by trapping them with pyridine; carbenic philicty; approach to a persistent triplet carbene; diaminocarbenes; exploring structure and reactivity; stable versions of transient singlet carbines; the discovery and development of high oxidation state alkylidene complexes; Fischer carbene complexes in organic synthesis; from high-spin polycarbenes to carbene-based magnets.