Description
Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes
Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes.
The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource:
- Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes
- Contains information from leading experts on the topic
- Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes
- Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds
Table of Contents
About the editors
List of contributors
Preface
Armando J.L. Pombeiro and M. Fátima C. Guedes da Silva
Chapter 1 Alkane Functionalization: Introduction And Overview
Armando J.L. Pombeiro
PART I - C-O BOND FORMATION. HYDROXYLATION AND OTHER OXYGENATION REACTIONS
Chapter 2 Activation and oxidative functionalization of alkanes with noble-metal catalysts: Molecular mechanisms
Evgeniy G. Chepaikin
Chapter 3 Alkane-oxidizing systems based on metal complexes. Radical versus non-radical mechanisms
Georgiy B. Shul’pin
Chapter 4 Reactions of alkyl radicals in aqueous solutions
Dan meyerstein
Chapter 5 C–H bond oxidation with transition metal based carbene complexes
Bruno Dominelli, Anja C. Lindhorst,Fritz E. Kühn
Chapter 6 Alkane oxidation with C-scorpionate metal complexes
Luísa M. D. R. S. Martins
Chapter 7 Alkane oxidation with multinuclear heterometallic catalysts
Dmytro S. Nesterov, Oksana V. Nesterova and Armando J.L. Pombeiro
Chapter 8 Oxidative functionalization of methane on heterogeneous catalysts
Maricruz Sanchez-Sanchez and Johannes A. Lercher
Chapter 9 Gas-phase oxidation of alkanes
Fabrizio Cavani, Alessandro Chieregato, Jose Manuel Lopez Nieto,Jean-Marc M. Millet
PART II - BIOINSPIRED ALKANE FUNCTIONALIZATION
Chapter 10 Recent developments of bio-inspired approaches to functionalization of light alkanes
Alexander B. Sorokin
Chapter 11 Regioselectivity of non-heme iron catalysts for C-H activation
Christian R. Goldsmith
Chapter 12 Imine-based Iron and Manganese Complexes as Catalysts for Alkane Functionalization
Giorgio Olivo, Osvaldo Lanzalunga,Stefano Di Stefano
Chapter 13 Alkane oxidation with biologically inspired nonheme iron catalysts based in the triazacyclononane ligand scaffold
Miquel Costas
Chapter 14 The nature of high-valent oxometal intermediates of iron-aminopyridine mediated oxidations
Oleg Y. Lyakin, konstantin P. Bryliakov, Evgenii P. Talsi
Chapter 15 Selective Oxidation of Alkanes by Metallo-Monooxygenases and their Nano-Biomimetics
Chih-Cheng Liu,Yi-FangTtsai,Wondemagegn H. Wanna,Ravirala Ramu, Damodar Janmanchi, Sunney I. Chan,Steve S.-F. Yu
Chapter 16 Alkane oxidation with vanadium and copper catalysts
Manas Sutradhar, Luísa M.D.R.S. Martins, M. Fátima C. Guedes da Silva, ArmandoJ. L. Pombeiro
PART III – C-B, C-C AND C-N BOND FORMATION
Chapter 17 Catalytic borylation of methane: combining computational and high-throughput screening approaches to discover a new catalyst
Pavel Zatsepin, Dieter Sorsche, Seihwan Ahn,Mu-Hyun Baik, Daniel J. Mindiola
Chapter 18 Alkane carbonylation and carbene insertion reactions
Ana M. Faisca Phillips and Armando J. L. Pombeiro
Chapter 19 Catalytic alkane amidation and related reactions
Dmytro S. Nesterov, Luís M. T. Frija, Armando J. L. Pombeiro, Maximilian N. Kopylovich
PART IV – DEHYDROGENATION REACTIONS
Chapter 20 Oxidative and non-oxidative routes to alkane dehydrogenation
Jay A. Labinger
Chapter 21 Dehydrogenation of alkanes using molecular catalysts
Huaquan Fang, Guixia Liu, Zheng Huang
PART V – UNCONVENTIONAL SYSTEMS
Chapter 22 Non-transition metal catalyzed oxidation of alkanes with peroxides
Maxim L. Kuznetsov
Chapter 23 Metal-free functionalization of alkanes
Jincan Zhao,Jianlin Han
Chapter 24 Alkane functionalization under unconventional conditions: in ionic liquid, in supercritical co2 and microwave assisted
Ana P.C. Ribeiro,Eelisabete C.B.A. Alegria, António Palavra,Aarmando J.L. Pombeiro
Chapter 25 Noncovalent interactions in alkane chemistry
Kamran T. Mahmudov,M. Fátima C. Guedes da Silva, Fedor I. Zubkov, Armando J. L. Pombeiro
Chapter 26 Alkane complexation
Robert H. Crabtree
Chapter 27 Alkane related C-H bond activation and functionalization of aliphatic amines
Christian Bruneau, Mathieu Achard
