Description
Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials.The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds.- Contains quality content edited, and contributed, by leading scholars in the field- Presents applied guidance on the preparation of original fluorinated compounds, potentially transferable from the lab scale to industrial applications- Provides practical synthesis information for a wide audience interested in fluorine compounds in many branches of chemistry, materials science, and physics
Table of Contents
1. The Cosmic Origin of Fluorine: An Astronomer's View on Fluorine Synthesis2. The Fluorine Atom in Health Care and Agrochemical Applications: A Contribution to Life Science3. Industrial Syntheses of Hydrohaloolefins and Related Products4. Electrochemical Fluorination: A Powerful Tool for the Preparation of Organofluorine Compounds5. Once Upon a Time Was the Langlois' Reagent: A "Sleeping Beauty6. Toward CF3S Group: From Trifluoromethylation of Sulfides to Direct Trifluoromethylthiolation7. Nucleophilic Di- and Trifluoromethylation of CO and CN Bonds8. Oxidative Trifluoromethylation and Trifluoromethylthiolation9. Catalytic Enantioselective Fluorination10. Development of Electrophilic Trifluoromethylating Reagents11. New Nucleophilic Fluoroalkylations12. Continuous Flow Selective Direct Fluorination Using Fluorine Gas13. Synthesis of Fluorinated Nitrogen-Containing Compounds Through Superelectrophilic Activation in Superacid HF/SbF514. Visible Light–Induced (Per)fluoroalkylation by Photoredox Catalysis15. Synthesis of Side Chain Fluorinated Amino Acids and Their Effects on the Properties of Peptides and Proteins16. Ionic Liquids and Polymers for Battery and Fuel Cells17. Strategic Incorporation of Fluorine for Drug Discovery and Development18. Telomerization Reaction of 3,3,3-Trifluoropropene19. High Oxidation States in Transition Metal Fluorides20. Photochemical Syntheses of Fluorides in Liquid Anhydrous Hydrogen Fluoride21. Sol–Gel Synthesis of Metal Fluorides: Reactivity and Mechanisms22. Solution-Based Synthesis of Nano-Sized TiO2 Anatase in Fluorinating Media23. Ionic Liquid Materials Based on Fluoroanions24. Reactivity of Surface Fluorinated TiO2 and TiAl Particles25. Chemical and Electrochemical Stability of Copper in Molten KF-2HF
