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Full Description
This book provides a comprehensive description of the catalytic technologies for selective hydrogenation of benzene to cyclohexene. Focusing on selective hydrogenation of benzene to prepare cyclohexene and its downstream products, such as cyclohexanone, bulk chemicals and high-value fine chemicals, it also discusses the objective laws, reaction mechanisms and scientific significance based on experimental data, analysis and characterization results. Given its scope, the book will appeal to a broad readership, particularly professionals at universities and scientific research institutes, senior undergraduates, master's and doctoral graduate students as well as practitioners in industry.
Contents
An overview of the catalytic selective hydrogenation technologies of benzene into cyclohexene.- Benzene selective hydrogenation thermodynamics, heterogeneous catalytic kinetics catalysis mechanism and scientific essence.- The first-generation catalyst for selective hydrogenation of benzene to cyclohexene-Ru-M- B/ZrO2(M=Fe, La) amorphous alloys.- The second-generation catalyst for selective hydrogenation of benzene to cyclohexene-Ru-Zn-Na2SiO3-PEG-10000.- Third-generation catalyst of benzene selective hydrogenation to cyclohexene—Ru-M (Zn, Mn, Fe, La, Ce) Nano-bimetallic system.- Fourth generation catalyst of benzene selective hydrogenation to cyclohexene—Ru-Zn@BZSS core-shell catalyst.- Modulation of activity and selectivity of the catalyst for benzene selective hydrogenation.- Catalyst deactivation and regeneration in benzene selective hydrogenation.- The catalytic technologies and key facilities for benzene selective hydrogenation.- Selective hydrogenation of benzene to cyclohexene and incorporate device of its downstream products.