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Full Description
This book presents a critical perspective of the applications of organometallic compounds (including those with metal or metalloid elements) and other related metal complexes as versatile functional materials in the transformation of light into electricity (solar energy conversion) and electricity into light (light generation in light emitting diode), in the reduction of carbon dioxide to useful chemicals, as well as in the safe and efficient production and utilization of hydrogen, which serves as an energy storage medium (i.e. energy carrier).
This book focuses on recent research developments in these emerging areas, with an emphasis on fundamental concepts and current applications of functional organometallic complexes and related metal-based molecules for energy research. With contributions from front-line researchers in the field from academia and industry, this timely book provides a valuable contribution to the scientific community in the field of energy science related to metal-based molecular materials.
Wai-Yeung Wong, PhD, is Chair Professor and Head of the Department of Chemistry at Hong Kong Baptist University, Hong Kong, P. R. China.
Contents
Organometallic versus organic molecules for energy conversion in organic LEDs and solar cells.- The interplay between theoretical methods and experiment in the design of organometallics for energy conversion.- First row transition metal complexes for the conversion of light into electricity and electricity into light.- Excited states energy flows and electron transfers in trans-bis(ethynyl)platinum(II)-containing polymers.- Metal porphyrinates for energy conversion.- Ruthenium(II) based sensitizers for DSC application.- Physical chemical approaches towards optimizing Gratzel-type dye-sensitized solar cells.- All-polymer solar cells.- New low-bandgap metal-containing polymers/oligomers for solar cell applications.- Transition-metal complexes for triplet-triplet annihilation-based energy upconversion.- Visible light-harvesting transition metal complexes for triplet-triplet annihilation upconversion.- Triarylboron functionalized metal complexes for OLEDs.- Organometallics for lighting or OLEDs.- WOLEDs using metal phosphors.- Organometallic catalysis in artificial photosynthesis.- Solar fuel via molecular water splitting catalysis.- Electrochemical oxidation of water catalyzed by metal complexes.- Hydrogen activation in water by organometallic complexes.- MOFs as platforms for hydrogen generation from chemical hydrides.- Organometallics for hydrogen storage applications.
