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基本説明
From the preface - Constitutional Dynamic Chemistry (CDC) and its application Dynamic Combinatorial Chemistry (DCC) are new evolutional approaches to produce chemical diversity. In contrast to the classical methods, they allow for the simple generation of functional systems amplified from a mixture of inter-exchanging architectures which result from sets of building blocks interacting reversibly. Kinetic or thermodynamic resolution, self-assembly followed by covalent modification, and phase-change processes all shed light on useful strategies to control and create convergence between self-organization and constitutional functions. Such dynamic libraries have special relevance for a very diverse range of applications such as drug-, catalyst-, and material discovery. CDC implements a dynamic molecular/supramolecular reversible interface between interacting constituents, mediating the structural self-correlation of different domains of generated systems by virtue of their basic constitutional behaviors. The self-assembly of the components controlled
by mastering molecular/supramolecular interactions may allow the flow of
structural information from molecular level toward nanoscale dimensions. This
volume of Topics in Current Chemistry focuses on constitutional methods for
understanding and controlling such upscale propagation of structural information...
Full Description
Constitutional Dynamic Chemistry: Bridge from Supramolecular Chemistry to Adaptive Chemistry, by Jean-Marie Lehn Multistate and Phase Change Selection in Constitutional Multivalent Systems, by Mihail Barboiu Dynamic Systemic Resolution, by Morakot Sakulsombat, Yan Zhang and Olof Ramström Dynamic Combinatorial Self-Replicating Systems, by Emilie Moulin and Nicolas Giuseppone DCC in the Development of Nucleic Acid Targeted and Nucleic Acid Inspired Structures, by Benjamin L. Miller Dynamic Nanoplatforms in Biosensor and Membrane Constitutional Systems, by Eugene Mahon, Teodor Aastrup und Mihail Barboiu Dynamic Assembly of Block-Copolymers, by D. Quémener, A. Deratani und S. Lecommandoux Dynamic Chemistry of Anion Recognition, by Radu Custelcean Supramolecular Naphthalenediimide Nanotubes, by Nandhini Ponnuswamy, Artur R. Stefankiewicz, Jeremy K. M. Sanders und G. Dan Pantoş Synthetic Molecular Machines and Polymer/Monomer Size Switches that Operate Through Dynamic and Non-Dynamic Covalent Changes, by Adrian-Mihail Stadler und Juan Ramírez Reversible Covalent Chemistries Compatible with the Principles of Constitutional Dynamic Chemistry: New Reactions to Create More Diversity, by Kamel Meguellati und Sylvain Ladame.
Contents
Jean-Marie Lehn
Constitutional Dynamic Chemistry: Bridge from Supramolecular Chemistry to Adaptive Chemistry.-
Mihail Barboiu
Multistate and Phase Change Selection in Constitutional Multivalent Systems.-
Morakot Sakulsombat
Yan Zhang
Olof Ramström
Dynamic Systemic Resolution.-
Emilie Moulin
Nicolas Giuseppone
Dynamic Combinatorial Self-Replicating Systems.-
Benjamin L. Miller
DCC in the Development of Nucleic Acid Targeted and Nucleic Acid Inspired Structures.-
Eugene Mahon
Teodor Aastrup
Mihail Barboiu
Dynamic Nanoplatforms in Biosensor and Membrane Constitutional Systems.-
D. Quémener
A. Deratani
S. Lecommandoux
Dynamic Assembly of Block-Copolymers.-
Radu Custelcean
Dynamic Chemistry of Anion Recognition.-
Nandhini Ponnuswamy
Artur R. Stefankiewicz
Jeremy K. M. Sanders
G. Dan Pantoş
Supramolecular Naphthalenediimide Nanotubes.-
Adrian-Mihail Stadler
Juan Ramírez
Synthetic Molecular Machines and Polymer/Monomer Size Switches that Operate Through Dynamic and Non-Dynamic Covalent Changes
Kamel Meguellati
Sylvain Ladame
Reversible Covalent Chemistries Compatible with the Principles of Constitutional Dynamic Chemistry: New Reactions to Create More Diversity.
