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Full Description
Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples.
This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.
Contents
Hydroformylation.- Asymmetric Hydroformylation.- Synthetic Applications of Tandem Reaction Sequences Involving Hydroformylation.- Hydroxy- and Alkoxycarbonylations of Alkenes and Alkynes.- Carbonylation of Ethene in Methanol Catalysed by Cationic Phosphine Complexes of Pd(II): from Polyketones to Monocarbonylated Products.- The Pauson-Khand Reaction.- Acetic Acid Synthesis by Catalytic Carbonylation of Methanol.- Carbonylations of Aldehydes.- Carbonylation of Epoxides.- Oxidative Carbonylations.
