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基本説明
Contents: The Diversity of Naturally Occurring Organohalogen Compounds.- The Global Cycles of the Naturally Occurring Monohalomethanes.- The Biogeochemistry of Chlorine in Soil.- and more.
Full Description
This book summarizes the state-of-the-art knowledge on naturally occurring organohalogens, of which more than 3700 are documented. The chapters cover all aspects of this field, including the structural diversity and sources of organohalogens, the mechanisms for their formation and biodegradation, the clinical use of dichloroacetate, and the synthesis of the powerful anticancer chlorine-containing cryptophycin. Both biogenic and abiogenic sources of organohalogens are treated, the latter of which include volcanic emissions and abiogenic formation in soil. Halogenation in humans, fungi, and in the ocean are covered in separate chapters. Sources and biosynthesis of the relatively rare natural organofluorines are also discussed in this volume. By better understanding of the role nature plays in the area of organohalogens, we can more intelligently regulate the production, use, and disposal of man-made organohalogen compounds.
Table of Contents
Introduction XIII
The Diversity of Naturally Produced
Organohalogens
Gordon W. Gribble 1 (16)
The Global Cycles of the Naturally Occurring
Monohalomethanes
David B. Harper and John T. G. Hamilton 17 (26)
The Biogeochemistry of Chlorine in Soil
Gunilla ヨberg 43 (20)
Abiotic Formation of Organohalogens During
Early Diagenetic Processes
Heinz F Sch er and Frank Keppler 63 (22)
Marine Sources of Volatile Organohalogens
Robert M. Moore 85 (18)
An Update on Organohalogen Metabolites Produced
by Basidiomycetes
Jim A. Field and Joannes B.P.A. Wijnberg 103 (18)
Volcanic Formation of Halogenated Organic
Compounds
Armin Jordan 121 (20)
Fluorinated Natural Products: Occurrence and
Biosynthesis
David B. Harper, David O'Hagan and Cormac D. 141 (30)
Murphy
Enzymology and Molecular Genetics of Biological
Halogenation
Karl-Heinz van P馥 and Susanne Zehner 171 (30)
Myeloperoxidase and Eosinophil Peroxidase:
Phagocyte Enzymes for Halogenation in Humans
Jeffrey P. Henderson and Jay W. Heinecke 201 (14)
Biotransformation, Toxicology and
Pharmacogenomics of Dichloroacetate
Chandramohan V. Ammini and Peter W. Stacpoole 215 (20)
The Natural Destruction of Organohalogen
Compounds. Environmental Dehalogenation
Charles E. Castro 235 (30)
Cryptophycin Synthesis
Marcus A. Tius 265 (42)
Subject Index 307