Heterogeneous Kinetics : Theory of Ziegler-Natta-Kaminsky Polymerization (Springer Series in Chemical Physics Vol.77) （2004. XIII, 264 p. w. 178 figs.）

Keii, T.

SPRINGER, BERLIN（2004発売）

• 製本 Hardcover:ハードカバー版／ページ数 264 p., 178 illus.
• 商品コード 9783540229575

Full Description

This book, aimed at academic and industrial scientists, presents the most advanced theory and methods of chemical kinetics. The theory is explained on the basis of the author's historical and logical view of traditional kinetics, beginning with van't Hoff and S. Arrhenius and progressing to the work of H. Eyring, E. Wigner and J. Horiuti. The theory has been applied to the understanding of Ziegler-Natta-Kaminsky catalysis, the results being supported by the author's own experimental studies. Organic chemists interested in finding new active catalysts will learn from this text how to understand the fundamental and practical kinetic method as relevant for catalyst research in industry and universities.

Contents

The Nature of Chemical Kinetics.- Thermodynamics of Chemical Reactions.- Experimental Methods and Treatment of Data.- Theory of Complex Reactions: Reaction Path.- Theory of Elementary Reactions.- Coordination Equilibrium and Kinetics.- Traditional Kinetics of Ziegler-Natta-Kaminsky Polymerization.- Coordination Kinetics of Ziegler-Natta-Kaminsky Polymerization.- Homogeneous Polymerization.- Propene Polymerization with Heterogeneous Ziegler-Natta Catalysts.- Kinetic Mechanism of Molecular Weight Distribution and Isotacticity.