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Full Description
Comprehensive reference on surface and interfacial defects reviewing energy production and storage as well as numerous applications
Surface and Interfacial Defects in Nanomaterials for Sustainable Energy Production and Storage covers novel aspects involving important electrocatalytic reactions based on defects and interface engineering on nanomaterials, providing a comprehensive exposition on various energy aspects. More than a collection of current advances, this work articulates a scientific vision in which atomic-level control of matter is no longer optional but essential to achieving significant improvements in efficiency, durability, and sustainability. By integrating emerging knowledge across disciplines, this volume sets the stage for a new paradigm in materials science, where structural imperfections become a tool, and the interface becomes a platform for innovation.
After providing the fundamentals of electrocatalysis and classical electrocatalysis, this book introduces defect and interface engineering theory as a new method to achieve high performance. It discusses the analysis on energy production and storage based on recent findings and perspectives and reviews prospects for future development.
Surface and Interfacial Defects in Nanomaterials for Sustainable Energy Production and Storage explores sample topics including:
Types, formation, and impact of surface defects and interfacial defects
Advanced characterization techniques, computational modeling, and defect healing and control strategies
Heterojunction hybrid catalysts for hydrogen production
Various applications including fuel production, fuel cells, electrolyzers, oxygen reduction, and Li-ion, Na-ion, K-ion, Li-air, and Zinc-air batteries
Performance enhancement in metal oxide-based electrochemical supercapacitors
Integrating knowledge across related fields in a cohesive manner, Surface and Interfacial Defects in Nanomaterials for Sustainable Energy Production and Storage offers a comprehensive understanding of the subject for materials scientists and chemists across various disciplines.
Contents
Part 1. Fundamentals
Chapter 1: Fundamentals of Nanomaterials in Energy Systems
1.1 Nanoscale Morphology: An In-depth Exploration
1.2 Energy Landscape Analysis: Challenges and Prospects
1.3 Role of Surface and Interfacial Defects in Nanomaterials
Chapter 2: Basics of Surface Defects: Types, Formation, and Impact
2.1. Classification of Surface Defects: A Comprehensive Taxonomy
2.2. Formation mechanism of surface defects
2.3 Engineering Surfaces: Strategies for Performance Enhancement
2.4 Impact of surface defects on material properties
Chapter 3: Fundamentals of Interfacial Defects: Types, Formation, and Impact
3.1 Categorization of Interfacial Defects
3.2 Mechanism of formation of interfacial defects
3.3 Impact of material properties
3.4 Engineering Interfaces for Improved Functionality
Chapter 4: Thermodynamics and Kinetics of Formation of Surface Defects and Interfacial Defects
4.1 Thermodynamics of effect formation
4.2 Kinetics if defect formation
4.3 Thermodynamic and kinetic control of defect formation
Chapter 5: Defects as Catalytic Sites in Energy Chemistry
5.1 Defect-Mediated Catalysis: Principles and Mechanisms
5.2 Engineering Catalytic Nanomaterials via Defect Manipulation
Chapter 6: Advanced Characterization Techniques for Defect and Interface Engineering
6.1 State-of-the-art for characterization techniques for surface and interfacial defects
6.2 Characterization methods for surface defects and interfacial defects highlighting their capabilities, limitations, and the critical insights they offer into engineering surface defects and some applications
6.3 Characterization methos for quantified the number and type of surface defects and their effect on the surface defects and properties of materials.
Chapter 7: Computational Modeling of Defects in Nanomaterials
7.1 Atomistic Modeling Approaches for Studying Defects
7.2 Simulation Techniques in Unraveling Defect Behavior
7.3 Correlation Between Computational Predictions and Experimental Observations
Chapter 8: Defect Healing and Control Strategies in Energy Systems
8.1 Approaches to Healing Surface and Interfacial Defects
8.2 Control Mechanisms for Minimizing Unintended Defects in Nanomaterials
8.3 Strategies for Sustainable Management of Defect-Related Issues
Chapter 9: Future Frontiers in Defect Science for Advanced Energy Technologies
9.1 Evolving Paradigms: Trends and Prospects in Defect-Driven Nanomaterials
9.2 Intersection with Other Disciplines: Collaborations and Synergies
9.3 Roadmap for Future Research in Surface and Interfacial Defects in Nanomaterials
Part 2. Defects and Interface Engineering in Energy Conversion
Chapter 10. Defect and Interface Engineering in Hydrogen Production
10.1 Defects in Catalytic Hydrogen Production
10.2 Interface Modulation for Improved Charge Transfer
10.3 Defect-Mediated Pathways for Hydrogen Evolution
10.4 Innovative Catalysts for Sustainable Hydrogen Synthesis
10.5 Defects and Interface Engineering in Electrochemical Hydrogen Production
Chapter 11. Defect and Interface Engineering in CO2 Reduction
11.1 Catalytic Site Modulation for CO2 Reduction
11.2 Interfacial Impact on CO2 Conversion
11.3 Defect-Engineered Catalysts for CO2 Valorization
11.4 Influence of Defects on Reaction Kinetics
Chapter 12. Defect and Interface Engineering in Fuel Production
12.1 Catalytic Defects in Alternative Fuel Synthesis
12.2 Interfacial Considerations in Fuel Production
12.3 Defect-Engineered Nanomaterials for Precision Fuel Synthesis
12.4 Innovative Catalysts for Sustainable Fuel Synthesis
12.5 Integration of Defects in Electrochemical Fuel Production
Chapter 13. Defect and Interface Engineering in Electrochemical Valorization
13.1 Catalytic Implications of Nanoscale Defects
13.2 Interface Optimization for Electrochemical Transformations
13.3 Defect-Driven Electrocatalysis
13.4 Strategic Modulation of Interfaces for Enhanced Selectivity
13.5 Defect and Interface Engineering for Feedstock-Specific Valorization
Chapter 14. Defect and Interface Engineering in Fuel Cells
14.1 Electrochemical Phenomena at the Defect Level
14.2 Tailoring Interfaces for Enhanced Fuel Cell Dynamics
14.3 Pioneering Catalysts through Defect Engineering
14.4 Interface-Mediated Efficiency Strategies
14.5 Challenges in High-Temperature Fuel Cells
Chapter 15. Defect and Interface Engineering in Electrolyzers
15.1 Synergistic Catalysis in Electrolysis
15.2 Precision Interface Engineering for Electrolytic Advancements
15.3 Revolutionizing Electrode Design with Defects
15.4 Advancements in Efficiency through Interface Engineering
15.5 Navigating Complexities in Cutting-Edge Electrolyzer Designs
Chapter 16. Defect and Interface Engineering for The Oxygen Reduction Reaction
Part 3. Defects and Interface Engineering in Energy Storage
Chapter 17. Defect and Interface Engineering in Li-ion batteries
17.1 Introduction to Metal-ion batteries,
17.2 Introduction to Li-ion Batteries and Defect Engineering
17.3 Defects in Li-ion Battery Materials
17.4 Interface Engineering in Li-ion Batteries
17.5 Defects and Electrochemical Performance
17.6 Strategies for Defect Control and Optimization
17.7 Impact of Defects on Charge Transport and Storage
17.8 Case Studies in Defect and Interface Engineering
17.9 Future Directions and Challenges
Chapter 18. Defect and Interface Engineering in Na-ion Batteries
18.1 Defect-Mediated Electrochemical Processes:
18.2 Interface Modulation for Enhanced Sodium-Ion Mobility
18.3 Defect-Engineered Electrode Materials
18.4 Interface-Mediated Stability and Cyclability Improvements
18.5 Defects and Interfaces in High-Energy-Density Na-ion Systems
18.6 Future Directions and Challenges in Na-ion Battery Defect Engineering
Chapter 19. Defect and Interface Engineering in K-ion Batteries
19.1 Potassium-Ion Kinetics and Defect Influence
19.2 Interface Engineering for Enhanced Potassium-Ion Migration
19.3 Defect-Engineered Electrode Materials
19.4 Interface-Mediated Stability and Prolonged Cyclability
19.5 Defects and Interfaces: Unraveling High-Capacity K-ion Systems
Chapter 20. Defect and Interface Engineering in Li-air Batteries
20.1 Electrochemical Dynamics of Li-air Systems
20.2 Defect-Driven Modulation of Lithium Reactivity
20.3 Interface Engineering for Precision Oxygen Reaction
20.4 Defect-Induced Stability Enhancements
20.5 Interfaces and Long-Term Cyclability in Li-air Systems
20.6 Future Perspectives in Defect and Interface Engineering for Li-air Batteries:
Chapter 21. Defect and Interface Engineering in Zinc-air Batteries
21.1 Fundamentals of Zinc-Air Battery Operation:
21.2 Defect-Driven Mechanisms in Zinc Reactivity:
21.3 Cutting-Edge Interface Engineering for Oxygen Reactions:
21.4 Innovative Defect-Induced Stability Strategies:
21.5 Advancements in Interface-Mediated Cyclability:
21.6 Frontier Research in Defect and Interface Engineering for Zinc-Air Batteries:
Chapter 22 Addressing Surface and Interfacial Defects in Lithium-sulfur Batteries
22.1 Overview of Li-S battery Technology
22.2 Impact of superficial and interfacial defects on the behavior of batteries Li-S
22.3 Optimizing defects to improve batteries Strategies for advantageously manipulating defects to promote ion flow, minimize side reactions, and improve structural strength are described.
22.4 Future and challenges of the Batteries Li-S
Chapter 23 Engineering Defects in Advanced Battery Systems
23.1 Introduction to Advanced Battery Technologies
23.2 Fundamentals of Defect Engineering in Batteries
23.3 Cases of studies: enhancing the performance of advance battery systems
23.4 Challenges and Future Perspectives in Defect Engineering
Chapter 24. Defect and Interface Engineering in Electrochemical Pseudocapacitors Based on Carbon
24.1 Carbon Structures in Electrochemical Pseudocapacitors: An Overview
24.2 Defect Engineering in 3D Carbon Frameworks
24.3 Defect and Interface Tailoring in 2D Carbon Configurations
24.4 1D Carbon Architectures: Defects and Interface Dynamics
24.5 Zero-Dimensional (0D) Carbon Nanostructures: A Defect and Interface Perspective
24.6 Advanced Characterization Techniques for Carbon-Based Pseudocapacitors
24.7 Future Prospects in Defect and Interface Engineering for Carbon-Based Pseudocapacitors
Chapter 25. Defect and Interface Engineering in Electrochemical Pseudocapacitors Based on Metal Oxides
25.1 Metal Oxides in Pseudocapacitors: Overview and Electrochemical Mechanisms
25.2 Defect Engineering Strategies in Metal Oxide Nanostructures
25.3 Interface Optimization in Metal Oxide Pseudocapacitors
25.4 Charge Storage Dynamics in Metal Oxide Pseudocapacitors
25.5 Defect-Driven Stability Enhancements in Metal Oxide Systems
25.6 Innovations and Future Perspectives in Metal Oxide Pseudocapacitors
Chapter 26. Defect and Interface Engineering in Electrochemical Pseudocapacitors Based on Pseudocapacitive Materials
26.1 Pseudocapacitive Materials Overview
26.2 Defect Engineering Strategies
26.3 Interface Tailoring
26.4 Charge Storage Dynamics
26.5 Innovations and Future Perspectives
