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Full Description
Comprehensive reference discussing synthesis, characterization, applications, and modeling strategies at the forefront of microgel/nanogels research
Micro and Nano Gels provides comprehensive interdisciplinary knowledge of micro/nano gels, discussing fundamental synthesis techniques, unique physicochemical properties and their assemblies (e.g. interfacial behaviors, behavior at oil/water or solid interfaces, colloidal packing, and internal morphologies), and innovative applications as adhesives, sensing agents, drug delivery vehicles, tissue scaffolds, optical devices, separation devices, catalytic reactors, and environmental remediation agents.
The book discusses recent advances on amphiphilic random copolymer micelles, focusing on the design, controlled self-assembly and dynamic self-sorting, and functional materials of random copolymer micelles in water. The book also reviews advances for both template-free and -based synthetic methods of nanogels and microgels, covering their mechanisms and enclosing building blocks, as well as advantages and disadvantages of different synthetic routes. Readers will find information on recent developments in microgel characterization using the most advanced tools available, notably scattering and microscopy techniques with nanoscale resolution.
Contributed to by top theoretical and experimental researchers in the field, Micro and Nano Gels includes information on:
How to combine experimental scattering techniques, such as small-angle scattering and neutron reflectometry, with in silico computer simulations to characterize the structure and response of soft compressible microgels
Nanostructure and dynamic behavior of microgels using high-speed atomic-force microscopy
Dynamics of microgels and their pastes with varying concentrations of microgels evaluated using dynamic light scattering
Simulations of soft colloids and the applicability of different network models for mesoscale studies
Micro and Nano Gels is an essentiala valuable reference on the subject for chemists and materials scientists to not only propel the advancement of pre-existing applications in such as coatings and cosmetics, but also facilitate the development of unprecedented applications.
Contents
Part I Introduction
1 Anisotropic, adaptive microgels: are they special?
Part II Synthesis
2 Ionic microgels
3 Precision polymerization of microgels
4 Reactions at the Interface
5 Thermosensitive microgels as ?active? nanoreactors for catalytic active metal/metal oxide nanoparticles
6 Design and fabrication of stimuli-responsive, nanocomposite hydrogel microspheres
7 Adaptive colloidal catalysts based on stimuli-responsive microgels
8 Internal structure of core-shell microgels as analyzed by small angle neutron scattering and dSTORM
Part III Characterization
9 Nanoscale optical imaging of individual and densely packed microgel colloids
10 Densely packed thermoreponsive microgels with size-, stiffness- and chemical dissimilarities: Rheology and colloidal gelation
11 Internal structure analysis of microgels
12 Structure and dynamics of microgels
13 Surface structure, mechanics and rheology of microgels
14 Scattering from microspheres and their assembly
15 Theory and computer simulation
16 Computer simulation
17 Electrophoretic behavior of soft particles
Part IV Interface and assembly
18 Optical properties of core-shell microgels: Experimental and theoretical insights into the volume phase transition
19 Phase transitions in interfacial assemblies of microgels
20 Microgels at fluid interfaces: Adsorption kinetics and interfacial biocatalysis
21 Responsive microgels-based colloidosomes
22 Self-assembly of microgels
Part V Applications
23 Bioapplications
24 Kinetically trapped and chemically fueled protocells and coacervates by liquid/liquid phase separation
25 Poly (N-isopropylacrylamide)-based drug delivery platforms
26 Controlling electrostatic interactions between micro- and nano-gel particles and counter ions by tuning polymerization conditions
27 Nanoparticles in living mice for cancer therapy
28 Ultra-low crosslinked microgels with clickable cores
29 Synthesis and characterization of microgels for drug delivery and tissue engineering applications
30 Synthesis and characterization of polymers and nanomaterials for drug delivery, imaging, and other biomedical applications
31 Starch nanogel assemblies for multi-stage drug delivery
32 Developing biomaterials for regenerative medicine and biosensing applications
33 Self-assembled nanogels and nanogel tectonic materials for biomedical applications
34 Design of bimolecularly stimuli-responsive microgels and nanogels using dynamic crosslinks
35 Electroactive Microgels
36 Industrial applications
