RAFT重合:方法・総合・応用(全2巻)<br>RAFT Polymerization : Methods, Synthesis and Applications (1. Auflage)

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RAFT重合:方法・総合・応用(全2巻)
RAFT Polymerization : Methods, Synthesis and Applications (1. Auflage)

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  • 製本 Hardcover:ハードカバー版/ページ数 1108 p.
  • 商品コード 9783527344956

Full Description

Explore this one-stop resource for reversible addition-fragmentation chain transfer polymerization from a leading voice in chemistry 

RAFT Polymerization: Methods, Synthesis and Applications delivers a comprehensive and insightful analysis of reversible addition-fragmentation chain transfer polymerization (RAFT) and its applications to fields as diverse as material science, industrial chemistry, and medicine. This one-stop resource offers readers a detailed synopsis of the current state of RAFT polymerization.  

This text will inspire further research and continue the drive to an ever-increasing range of applications by synthesizing and explaining the more central existing literature on RAFT polymerization. It contains a beginner's guide on how to do a RAFT polymerization before moving on to much more advanced techniques and concepts, like the kinetics and mechanisms of the RAFT process. The distinguished editors have also included resources covering the four major classes of RAFT agents and recent developments in processes for initiating RAFT polymerization. Readers will also benefit from the inclusion of: 



A thorough introduction to the mechanisms, theory, and mathematical modeling of RAFT 
Explorations of RAFT agent design and synthesis, dithioesters, dithiobenzoates, trithiocarbonates, xanthates, dithiocarbamates, macromonomer RAFT, and RAFT copolymerization 
Discussions of a variety of RAFT architectures, including multiblocks, combs, hyperbranched polymers, and stars 
Treatments of end group transformation, cationic RAFT, high-throughput RAFT, and RAFT in continuous flow 
An examination of sequence defined polymers by RAFT 

Perfect for organic chemists, polymer chemists, and materials scientists, RAFT Polymerization: Methods, Synthesis and Applications will also earn a place in the libraries of chemical engineers seeking a one-stop reference for this method of controlled radical polymerization with a wide range of applications in multiple areas. 

 

Contents

Overview

Terminology in Reversible Deactivation Radical Polymerization (RDRP) and Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization.

How to do a RAFT Polymerisation

Kinetics and Mechanism of RAFT Polymerizations

RAFT Mechanisms

Quantum-Chemical Studies of RAFT Polymerization

Mathematical Modeling of RAFT Polymerization

Dithioesters in RAFT Polymerization

Trithiocarbonates in RAFT Polymerization

Xanthates in RAFT Polymerization

Dithiocarbamates in RAFT Polymerization

Photo RAFT Polymerization

Redox initiated RAFT Polymerization and (Electro)Chemical Activation of RAFT Agents

Considerations for and Applications of Aqueous RAFT Polymerization

RAFT-Mediated Polymerization-Induced Self-Assembly (PISA)

RAFT Functional End-Groups: Installation and Transformation

Sequence-Encoded RAFT oligomers and polymers

Synthesis and Application of Reactive Polymers via RAFT Polymerization

RAFT Crosslinking Polymerization

Complex Polymeric Architectures Synthesised through RAFT Polymerization

Star Polymers by RAFT Polymerization

Surface and Particle Modification via RAFT Polymerization: An Update

High Throughput / High Output Experimentation in RAFT Polymer Synthesis

An Industrial History of RAFT Polymerization

Cationic RAFT Polymerization