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Full Description
In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.
Contents
Chapter-I: Steric and stereoelectronic control of molecular structures and organic reactions.- Chapter-II. Reactions at saturated and unsaturated carbon.- Chapter-III: Diastereoselectivity in organic reactions.- Chapter-IV: A(1,2) and A(1,3) strains.- Chapter-V: The conservation of orbital symmetry (Woodward-Hoffmann rules).- Chapter-VI: The overlap component of the stereoelectronic factor vis-à-vis the conservation of orbital symmetry rules.- Chapter VII: Torquoselectivity of conrotatory ring opening in 3-substituted cyclobutenes.- Chapter-VIII: Hammett Substituent Constants.- Chapter-IX. Relative aromaticity of pyrrole, furan, thiophene and selenophene, and their Diels-Alder stereoselectivity.- Chapter-X: Miscellaneous.
