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Full Description
Volumes in the Proven Synthetic Methods Series address the concerns many chemists have regarding irreproducibility of synthetic protocols, lack of identification and characterization data for new compounds, and inflated yields reported in chemical communications—trends that have recently become a serious problem.
Featuring contributions from world-renowned experts and overseen by a highly respected series editor, Carbohydrate Chemistry: Proven Synthetic Methods, Volume 4 compiles reliable synthetic methods and protocols for the preparation of intermediates for carbohydrate synthesis or other uses in the glycosciences.
Exploring carbohydrate chemistry from both the academic and industrial points of view, this unique resource brings together useful information into one convenient reference. The series is unique among other synthetic literature in the carbohydrate field in that, to ensure reproducibility, an independent checker has verified the experimental parts involved by repeating the protocols or using the methods.
The book includes new or more detailed versions of previously published protocols as well as those published in not readily available journals. The essential characteristics of the protocols presented are reliability, updated characterization data for newly synthesized substances and the expectation of wide utility in the carbohydrate field. The protocols presented will be of wide use to a broad range of readers in the carbohydrate field and the life sciences, including undergraduates taking carbohydrate workshops.
Contents
ForewordIntroductionEditorsSeries EditorContributorsSection I Synthetic MethodsChapter 1 Picoloyl-Protecting Group in Oligosaccharide Synthesis: Installation, H-Bond-Mediated Aglycone Delivery (HAD), and Selective RemovalMichael P. Mannino, Jagodige P. Yasomanee, Alexei V. Demchenko, and Venukumar PattetiChapter 2 Monomethoxytrityl (MMTr) as an Efficient S-Protecting Group in the Manipulation of Glycosyl ThiolsRaymond Smith, Xiangming Zhu, and Elena Calatrava-PérezChapter 3 One-Step Inversion of Configuration of a Hydroxy Group in CarbohydratesShino Manabe and Markus BlaukopfChapter 4 Formation and Cleavage of Benzylidene Acetals Catalyzed by NaHSO4?SiO2Lifeng Sun, Xin-Shan Ye, and Xingdi WangChapter 5 Thiodisaccharides by Photoinduced Hydrothiolation of 2-Acetoxy GlycalsDániel Eszenyi, László Lázár, Anikó Borbás, andRuairi O. McCourtChapter 6 One-Step Preparation of Protected N-tert-Butanesulfinyl d-ribo and d-xylo Furanosylamines from Related Sugar HemiacetalsChloé Cocaud, Cyril Nicolas, Olivier R. Martin, and Jérôme DésiréChapter 7 An Alternative Preparation of Azides from Amines via Diazotransfer with Triflyl AzideYuqian Ye, Xin-Shan Ye, and Xingdi WangChapter 8 Simple Preparation of Dimethyldioxirane and Its Use as an Epoxidation Agent for the Transformation of Glycals to Glycosyl PhosphatesKatharina Kettelhoit, Daniel B. Werz, Aniruddha Sasmal, Xinyu Liu, and Philipp GritschChapter 9 Preparation of Glycosyl Bromides of ?-d-Gluco-hept-2-ulopyranosonic Acid DerivativesVeronika Nagy, Katalin Czifrák, László Juhász, László Somsák, and Olena ApeltChapter 10 Preparation of 2,6-Anhydro-hept-2-enonic Acid Derivatives and Their 3-Deoxy Count
