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基本説明
This new third edition continues to address environmental concerns and green polymeric materials but also adds new material on health concerns of additives as well as additional information on the use of microbes for monomer synthesis and cracking processes in fuels.
Full Description
Continuing the tradition of its previous editions, the third edition of Introduction to Polymer Chemistry provides a well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this third edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, biomacromolecules, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Using simple fundamentals, the book demonstrates how the basic principles of one polymer group can be applied to all of the other groups. It covers reactivities, synthesis and polymerization reactions, techniques for characterization and analysis, energy absorption and thermal conductivity, physical and optical properties, and practical applications. This edition addresses environmental concerns and green polymeric materials, including biodegradable polymers and microorganisms for synthesizing materials. Case studies woven within the text illustrate various developments and the societal and scientific contexts in which these changes occurred.Now including new material on environmental science, Introduction to Polymer Chemistry, Third Edition remains the premier book for understanding the behavior of polymers. Building on undergraduate work in foundational courses, the text fulfills the American Chemical Society Committee on Professional Training (ACS CPT) in-depth course requirement.
Contents
Introduction to PolymersHistory of PolymersWhy Polymers?Today's MarketplaceEnvironmental AssessmentManaging SustainabilityGeneral Encyclopedias and DictionariesPolymer Structure (Morphology)Stereochemistry of PolymersMolecular InteractionsPolymer CrystalsAmorphous Bulk StatePolymer Structure-Property RelationshipsCrystalline and Amorphous CombinationsCrosslinkingMolecular Weight of PolymersIntroductionSolubilityAverage Molecular Weight ValuesFractionation of Polydisperse SystemsChromatographyColligative Molecular WeightsLight-Scattering PhotometryOther TechniquesViscometryNaturally Occurring PolymersPolysaccharidesCelluloseCellulose-Regenerating ProcessesEsters and Ethers of CelluloseStarchOther PolysaccharidesProteinsNucleic AcidsNaturally Occurring Polyisoprenes and Other Synthetic ElastomersLigninMelaninsPolymer StructureGenetic EngineeringDNA ProfilingAsphaltStep-Reaction Polymerization (Polycondensation Reactions)Comparison between Polymer Type and Kinetics of PolymerizationIntroductionStepwise KineticsPolycondensation MechanismsPolyesters and PolycarbonatesSynthetic PolyamidesPolyimidesPolybenzimidazoles and Related PolymersPolyurethanes and PolyureasPolysulfidesPolyethersPolysulfonesPoly(Ether Ether Ketone) and PolyketonesPhenolic and Amino PlasticsSynthetic RoutesLiquid CrystalsMicrofibersIonic Chain-Reaction and Complex Coordination Polymerization (Addition Polymerization)Cationic PolymerizationAnionic PolymerizationStereoregularity and StereogeometryPolymerization with Complex Coordination CatalystsSoluble Stereoregulating CatalysisPolyethylenesPolypropylenePolymers from 1,4-DienesPolyisobutyleneMetathesis ReactionsZwitterionic PolymerizationIsomerization PolymerizationPrecipitation PolymerizationFree Radical Chain Polymerization (Addition Polymerization)Initiators for Free Radical Chain PolymerizationMechanism for Free Radical Chain PolymerizationChain TransferPolymerization TechniquesFluorine-Containing PolymersPolystyrenePoly(Vinyl Chloride)Poly(Methyl Methacrylate)PolyacrylonitrileSolid-State Irradiation PolymerizationPlasma PolymerizationsCopolymerizationKinetics of CopolymerizationThe Q-e SchemeCommercial CopolymersBlock CopolymersGraft CopolymersElastomersBlendsPolymer Mixtures: IPNS and AlloysDendritesIonomersFluoroelastomersNitrile RubberAcrylonitrile Butadiene Styrene TerpolymersEPDM RubberOrganometallic and Metalloid PolymersIntroductionInorganic Reaction MechanismsCondensation Organometallic PolymersCoordination PolymersAddition PolymersInorganic PolymersIntroductionPortland CementOther CementsSilicatesSilicon Dioxide (Amorphous)Sol-GelSilicon Dioxide (Crystalline Forms): Quartz FormsSilicon Dioxide in Electronic ChipsAsbestosFly Ash and AluminosilicatesPolymeric Carbon: DiamondPolymeric Carbon: GraphiteInternal Cyclization: Carbon Fibers and Related MaterialsCarbon NanotubesBitumensCarbon BlackPolysulfurCeramicsHigh-Temperature SuperconductorsZeolitesReactions of PolymersReactions with Polyolefins and PolyenesReactions of Aromatic and Aliphatic Pendant GroupsDegradationCross-LinkingReactivities of End GroupsSupramolecules and Self-AssemblyTransfer and Retention of OxygenNature's Macromolecular CatalystsPhotosynthesisMechanisms of Energy Physical AbsorptionBreakage of Polymeric MaterialsTesting and Spectrometric Characterization of PolymersSpectronic Characterization of PolymersSurface CharacterizationAmorphous Region DeterminationsThermal AnalysisThermal Property TestsFlammabilityElectrical Properties: TheoryElectric MeasurementsWeatherabilityOptical Properties TestsChemical ResistanceRheology and Physical TestsRheologyTypical Stress-Strain BehaviorStress-Strain RelationshipsSpecific Physical TestsAdditivesFillersReinforcementsNanocompositesPlasticizersAntioxidantsHeat StabilizersUltraviolet StabilizersFlame RetardantsColorantsCuring AgentsAntistatic Agents: AntistatsChemical Blowing AgentsCompatibilizersImpact ModifiersProcessing AidsLubricantsMicroorganism InhibitorsSynthesis of Reactants and Intermediates for PolymersMonomer Synthesis from Basic FeedstocksReactants for Step-Reaction PolymerizationSynthesis of Vinyl MonomersPolymer TechnologyPolymer ProcessingSecondary Structures: MesophasesFibersElastomersFilms and SheetsPolymeric FoamsReinforced Plastics (Composites) and LaminatesMoldingCastingExtrusionCoatingsAdhesivesConductive Polymeric MaterialsDrug Design and ActivitySynthetic Biomedical PolymersDental MaterialsEmerging PolymersGreen MaterialsAppendicesStructures of Common PolymersSymbolsComments on Health and Toxicological Aspects of PolymersISO 9000 and 14000Web Resources