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TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen- tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants. Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors. Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg- ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe- ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage- mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V. ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo- gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi- neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent.
Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice. Thecontributionspresented in thisvolumearedivided intofourseparatebutcom- plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment. D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium. ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron- mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition. Thisgener- osity was essential to the overall successofthe symposium and is gratefully acknow- ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview...FrederickG.
PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants...9 MiratD. Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S. A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F. C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R. W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction ...69 GuyoungKang,JimoJung,KapsongPark,andDavidK. Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW. Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage...91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9. BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K. Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P. G. Chaphalkar,K. T. Valsaraj,D.
Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG. PavlostathisandPingZhuang SeparationTechnologies 12. TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses ...
Contents
1. Emerging Technologies in Hazardous Waste Management VII: An Overview.- Chemical and Thermal Methods.- 2. Granular Iron Oxide as a Catalyst in Chemical Oxidation of Organic Contaminants.- 3. An Electron Beam Generated Plasma Reactor for Decomposition of Halogenated VOCs.- 4. Incineration and Thermal Treatment of Chemical Agents and Chemical Weapons.- 5. Predicting Stability Constants of Various Chelating Agents Using QSAR Technology.- 6. Mineralization of Hazardous Chemicals by Heme Reaction.- Biochemical Treatment.- 7. Anaerobic Transformations of Carbon Tetrachloride: Combined Bacterial and Abiotic Processes.- 8. Biorecovery of Metals from Acid Mine Drainage.- 9 Biotreatment of Minewater-Containing Cyanides by Using Immobilized Cell Technology.- 10. Augmentation ofin-SituSubsoil Remediation Using Colloidal Gas Dispersions.- 11. Effect of Sorption on the Microbial Reductive Dechlorination of Soil-Bound Chloroalkenes.- Separation Technologies.- 12. The Removal of VOCs from Exhaust Air and Vapour Condensates by Membrane Processes.- 13. Electrochemical Recovery of EDTA and Heavy Metals from Washing of Metal Contaminated Soil.- 14. Potential of Mosquito Fern(Azolla carolinianaWilld.) Plants as a Biofilter for Cadmium Removal from Wastewater.- 15. Extraction of Lead from Soil in ROTC Firing Ranges.- Radioactive Waste Treatment.- 16. Removal and Treatment of Radioactive, Organochlorine, and Heavy Metal Contaminants from Solid Surfaces.- 17. Electrolytic Decontamination of Conductive Materials for Hazardous Waste Management.
