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Full Description
The purpose of this series is to provide a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organo metallic reactions in solution, with coverage being complete in each volume. The papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms and many include results of a nonkinetic nature when useful mechanistic information can be deduced. The period of literature covered by this volume is July 1982 through December 1983, and in some instances papers not available for inclusion in the previous volume are also included. Numerical results are usually reported in the units used by the original authors, except where data from different papers are com pared and conversion to common units is necessary. As in previous volumes material included covers the major areas of redox processes, reactions of the nonmetallic elements, reaction of inert and labile metal complexes and the reactions of organometallic compounds. While maintaining the space devoted to other areas, that given to the nonmetallic elements has been increased. In recognition of the increasing importance of the determination of volumes of activation in understanding the mechanisms of both inorganic and organometallic reactions a special reference section giving tabulated Ll V* values has been included and this extensive compilation will be updated in future volumes.
Contents
1. Electron Transfer Reactions.- 1. Electron Transfer: General and Theoretical.- 2. Redox Reactions between Metal Complexes.- 3. Metal-Ligand Redox Reactions.- 2: Substitution and Related Reactions.- 4. Reactions of Compounds of the Nonmetallic Elements.- 5. Substitution Reactions of Inert-Metal Complexes— Coordination Numbers 4 and 5.- 6. Substitution Reactions of Inert-Metal Complexes— Coordination Numbers 6 and Above: Chromium.- 7. Substitution Reactions of Inert-Metal Complexes— Coordination Numbers 6 and Above: Cobalt.- 8. Substitution Reactions of Inert-Metal Complexes— Coordination Numbers 6 and Above: Other Inert Centers.- 9. Substitution Reactions of Labile Metal Complexes.- 3. Reactions of Organometallic Compounds.- 10. Substitution and Insertion Reactions of Organometallic Compounds.- 11. Metal-Alkyl Bond Formation and Fission; Oxidative Addition and Reductive Elimination.- 12. Reactivity of Coordinated Hydrocarbons.- 13. Rearrangements, Intramolecular Exchanges, and Isomerization of Organometallic Compounds.- 14. Homogeneous Catalysis of Organic Reactions by Complexes of Metal Ions.- 4. Compilations of Numerical Data.- 15. Volumes of Activation for Inorganic and Organometallic Reactions: A Tabulated Compilation.- References.- Author Index.
