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Full Description
This book explains how molecular movement is determined by chemical structure, then how motion controls the physical and technological properties of polymer materials. Readers are introduced to the concepts of molecular movement in polymers and the connections with causative chemical structure on the one hand and resulting bulk physical and technological behavior on the other. The approach is non-mathematical, but is molecularly based and allows readers to understand the detailed chemical and rigorous mathematical discussions of more advanced texts.
Contents
Introduction
Chemical structure of polymers
Molecular motion in polymers
The glass to rubber transition
The glass state
Crystallinity
The rubber state
The liquid/melt state
Drawing and fracture
Dynamic mechanical relaxation
Acoustic (ultrasonic) relaxation
Dielectric relaxation
Photophysics of polymers (excited state relaxation)
Conductivity in polymer systems
Diffusion in polymers
Methods of studying molecular motion