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Revised, updated, and rewritten where necessary, but keeping the clear writing and organizational style that made previous editions so popular, Elements of Environmental Engineering: Thermodynamics and Kinetics, Third Edition contains new problems and new examples that better illustrate theory. The new edition contains examples with practical flavor such as global warming, ozone layer depletion, nanotechnology, green chemistry, and green engineering. With detailed theoretical discussion and principles illuminated by numerical examples, this book fills the gaps in coverage of the principles and applications of kinetics and thermodynamics in environmental engineering and science. New topics covered include:Green Chemistry and EngineeringBiological ProcessesLife Cycle AnalysisGlobal Climate ChangeThe author discusses the applications of thermodynamics and kinetics and delineates the distribution of pollutants and the interrelationships between them. His demonstration of the theoretical foundations of chemical property estimations gives students an in depth understanding of the limitations of thermodynamics and kinetics as applied to environmental fate and transport modeling and separation processes for waste treatment. His treatment of the material underlines the multidisciplinary nature of environmental engineering.This book is unusual in environmental engineering since it deals exclusively with the applications of chemical thermodynamics and kinetics in environmental processes. The book's multimedia approach to fate and transport modeling and in pollution control design options provides a science and engineering treatment of environmental problems.
Contents
IntroductionEnergy, Population, and PollutionEnvironmental Standards and CriteriaThe Discipline of Environmental EngineeringChemical Thermodynamics and Kinetics in EnvironmentalEngineeringUnits and DimensionsStructure of the Book ReferencesBasic Chemical Thermodynamics EquilibriumFundamental Laws of Thermodynamics Chemical Equilibrium and Gibbs Free Energy Concept of MaximumWork Gibbs Free Energy and Chemical PotentialThermodynamics of Surfaces and Colloidal SystemsProblemsReferencesMulticomponent Equilibrium ThermodynamicsIdeal and Nonideal FluidsFugacityIdeal Solutions and Dilute SolutionsNonideal SolutionsAdsorption on Surfaces and InterfacesProblemsReferencesApplications of Equilibrium ThermodynamicsAir-Water Phase EquilibriumAir-Water Equilibrium in Atmospheric ChemistrySoil-Water and Sediment-Water EquilibriumBiota/Water Partition Constant (Bioconcentration Factor)Air-to-Aerosol Partition ConstantAir-to-Vegetation Partition ConstantAdsorption on Activated Carbon forWastewater TreatmentProblemsReferencesConcepts from Chemical Reaction KineticsProgress Toward Equilibrium in a Chemical ReactionReaction Rate, Order, and Rate ConstantKinetic Rate LawsActivation EnergyReaction MechanismsReactions in SolutionsEnvironmental CatalysisRedox Reactions in Environmental SystemsEnvironmental Photochemical ReactionsEnzyme CatalysisProblemsReferencesApplications of Chemical Kinetics in Environmental SystemsTypes of ReactorsTheWater EnvironmentThe Air EnvironmentSoil and Sediment EnvironmentsApplications of Chemical Kinetics in EnvironmentalBioengineeringApplications in Green EngineeringProblemsReferencesAppendix 1: Properties of Selected Chemicals of Environmental SignificanceAppendix 2: Standard Free Energy, Enthalpy, and Entropy of Formation for Compounds of Environmental SignificanceAppendix 3: Selected Fragment (bj) and Structural Factors (Bk) for Octanol-Water Partition Constant EstimationAppendix 4: Concentration Units for Compartments in Environmental Engineering Appendix 5: Dissociation Constants for Environmentally Significant Acids and Bases Appendix 6: Bond Contributions to Log Kaw for the Meylan and Howard ModelAppendix 7: Regression Analysis (the Linear Least-Squares Methodology)Appendix 8: Error Function and Complementary Error Function DefinitionsAppendix 9: Cancer Slope Factor and Inhalation Unit Risk for Selected Carcinogens Appendix 10: U.S. National Ambient Air Quality StandardsIndex