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Full Description
Recipient of the 2019 Most Promising New Textbook Award from the Textbook & Academic Authors Association (TAA).
"The authors of Attainable Region Theory: An Introduction to an Choosing Optimal Reactor make what is a complex subject and decades of research accessible to the target audience in a compelling narrative with numerous examples of real-world applications." TAA Award Judges, February 2019
Learn how to effectively interpret, select and optimize reactors for complex reactive systems, using Attainable Region theory
Teaches how to effectively interpret, select and optimize reactors for complex reactive systems, using Attainable Region (AR) theory
Written by co-founders and experienced practitioners of the theory
Covers both the fundamentals of AR theory for readers new to the field, as we all as advanced AR topics for more advanced practitioners for understanding and improving realistic reactor systems
Includes over 200 illustrations and 70 worked examples explaining how AR theory can be applied to complex reactor networks, making it ideal for instructors and self-study
Interactive software tools and examples written for the book help to demonstrate the concepts and encourage exploration of the ideas
Contents
Preface xi
Acknowledgments xiii
Prior Knowledge xiv
How this book is Structured xv
Software and Companion Website xvii
Nomenclature xix
SECTION I BASIC THEORY 1
1 Introduction 3
1.1 Introduction 3
1.2 Motivation 3
1.3 Reactor Network Synthesis 8
1.4 Solving the Reactor Network Synthesis Problem 12
1.5 Chapter Review 16
References 17
2 Concentration and Mixing 19
2.1 Introduction 19
2.2 Concentration Vectors and Dimension 23
2.3 Mixing 28
2.4 Chapter Review 47
References 47
3 The Attainable Region 49
3.1 Introduction 49
3.2 A Mixing and Reaction Game 49
3.3 The AR 57
3.4 Elementary Properties of the AR 58
3.5 Chapter Review 61
References 61
4 Reaction 63
4.1 Introduction 63
4.2 Reaction Rates and Stoichiometry 63
4.3 Reaction from a Geometric Viewpoint 66
4.4 Three Fundamental Continuous Reactor Types 73
4.5 Summary 102
4.6 Mixing Temperatures 102
4.7 Additional Properties of the AR 105
4.8 Chapter Review 106
References 107
5 Two-Dimensional Constructions 109
5.1 Introduction 109
5.2 A Framework for Tackling AR Problems 109
5.3 Two-Dimensional Van De Vusse Kinetics 110
5.4 Multiple CSTR Steady States and ISOLAS 125
5.5 Constructions in Residence Time Space 131
5.6 Chapter Review 141
References 141
SECTION II EXTENDED TOPICS 143
6 Higher Dimensional AR Theory 145
6.1 Introduction 145
6.2 Dimension and Stoichiometry 146
6.3 The Three Fundamental Reactor Types Used in AR Theory 159
6.4 Critical DSRs and CSTRs 166
6.5 Chapter Review 189
References 190
7 Applications of AR Theory 191
7.1 Introduction 191
7.2 Higher Dimensional Constructions 191
7.3 Nonisothermal Constructions and Reactor Type Constraints 205
7.4 AR Theory for Batch Reactors 222
7.5 Chapter Review 232
References 233
8 AR Construction Algorithms 235
8.1 Introduction 235
8.2 Preliminaries 235
8.3 Overview of AR Construction Methods 246
8.4 Inside-out Construction Methods 248
8.5 Outside-in Construction Methods 262
8.6 Superstructure Methods 270
8.7 Chapter Review 279
References 279
9 Attainable Regions for Variable Density Systems 281
9.1 Introduction 281
9.2 Common Conversions to Mass Fraction Space 281
9.3 Examples 293
9.4 Chapter Review 298
References 299
10 Final Remarks Further Reading and Future Directions 301
10.1 Introduction 301
10.2 Chapter Summaries and Final Remarks 301
10.3 Further Reading 304
10.4 Future Directions 305
References 307
Appendix A Fundamental Reactor Types 309
A.1 The Plug Flow Reactor 309
A.2 The Continuous-Flow Stirred Tank Reactor 309
A.3 The Differential Sidestream Reactor 310
Appendix B Mathematical Topics 311
B.1 Set Notation 311
B.2 Aspects of Linear Algebra 311
B.3 The Complement Principle 313
References 315
Appendix C Companion Software and Website 317
C.1 Introduction 317
C.2 Obtaining Python and Jupyter 318
Index 321
